Synthetic meso-substituted porphyrins offer significant attractions compared with naturally
occurring β-substituted porphyrins. The attractions include the rectilinear arrangement of the …

De Novo Synthesis of Gem-Dialkyl Chlorophyll Analogues for Probing and Emulating Our Green
World | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In …

The utilization of metalloporphyrins as bioinspired oxidation catalysts is an evolving topic of
research. By understanding the cytochrome P-450 mechanism of action, chemists have …

Fully unsubstituted 4, 4-difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) 1 was prepared.
Reaction of 8-thiomethylbodipy 2 with triethylsilane in the presence of a catalytic amount of …

Fluorescent dyes are heavily sought for their potentials applications in bioimaging, sensing,
theranostic, and optoelectronic materials. Among them, BODIPY dyes are privileged …

Tetrapyrrole macrocycles are central to photosynthesis yet a single macrocycle does not
carry out photosynthesis; rather, assemblies of tetrapyrrole macrocycles work in concert in …

The synthetic chemistry of the pyrrolic unit is dominated by electrophilic aromatic substitution
and pyrrole is much more reactive than benzene in this respect, as a result of the lone pair at …

Dipyrranes constitute important building blocks in the synthesis of porphyrins, corroles,
chlorins, calix [4] pyrroles, porphodimethenes, BODIPY dyes and dipyrrinato complexes …

Formylation has been performed on pyrrole‐unsubstituted dipyrromethanes 1 and boron–
dipyrrin (BODIPY) dyes 4 based on a Vilsmeier–Haack reaction. It is highly regioselective …

Surface defects of perovskite films are the major sources of nonradiative recombination
which limit the efficiency and stability of perovskite solar cells. Surface passivation …