Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Current strategies and future perspectives in biological hydrogen production: A review

B Ramprakash, P Lindblad, JJ Eaton-Rye… - … and Sustainable Energy …, 2022 - Elsevier
Biohydrogen is a green and eco-friendly energy carrier with the potential to reduce our
dependency on fossil fuels. Renewable biohydrogen production from waste biomass …

Clostridium species for fermentative hydrogen production: an overview

J Wang, Y Yin - International Journal of Hydrogen Energy, 2021 - Elsevier
Dark fermentation is considered as a promising method for sustainable hydrogen
generation. Microorganisms play a pivotal role in hydrogen production efficiency. Strains …

Biological hydrogen with industrial potential: Improvement and prospection in biohydrogen production

W Chen, T Li, Y Ren, J Wang, H Chen… - Journal of Cleaner …, 2023 - Elsevier
Hydrogen is an important industrial material and ideal secondary energy. It is widely used in
petrochemical, electronics, metallurgy, food processing, fine organic synthesis, and clean …

The catalytic cycle of [FeFe] hydrogenase: A tale of two sites

JA Birrell, P Rodriguez-Macia, EJ Reijerse… - Coordination Chemistry …, 2021 - Elsevier
Ever since the discovery of hydrogenases over 90 years ago (Stephenson and Stickland,
1931), their structure and mechanism of action have been intensively investigated. Of the …

Fantastic [FeFe]-hydrogenases and where to find them

S Morra - Frontiers in Microbiology, 2022 - frontiersin.org
[FeFe]-hydrogenases are complex metalloenzymes, key to microbial energy metabolism in
numerous organisms. During anaerobic metabolism, they dissipate excess reducing …

Current state of [FeFe]-hydrogenase research: biodiversity and spectroscopic investigations

H Land, M Senger, G Berggren, ST Stripp - ACS catalysis, 2020 - ACS Publications
Hydrogenases are redox enzymes that catalyze the conversion of protons and molecular
hydrogen (H2). Based on the composition of the active site cofactor, the monometallic [Fe] …

A safety cap protects hydrogenase from oxygen attack

M Winkler, J Duan, A Rutz, C Felbek… - Nature …, 2021 - nature.com
Abstract [FeFe]-hydrogenases are efficient H2-catalysts, yet upon contact with dioxygen their
catalytic cofactor (H-cluster) is irreversibly inactivated. Here, we combine X-ray …

Hydrogenase and nitrogenase: key catalysts in biohydrogen production

J Xuan, L He, W Wen, Y Feng - Molecules, 2023 - mdpi.com
Hydrogen with high energy content is considered to be a promising alternative clean energy
source. Biohydrogen production through microbes provides a renewable and immense …

Probing Substrate Transport Effects on Enzymatic Hydrogen Catalysis: An Alternative Proton Transfer Pathway in Putatively Sensory [FeFe] Hydrogenase

PR Cabotaje, K Walter, A Zamader, P Huang, F Ho… - ACS …, 2023 - ACS Publications
[FeFe] hydrogenases, metalloenzymes catalyzing proton/dihydrogen interconversion, have
attracted intense attention due to their remarkable catalytic properties and (bio-) …