New Horizon in Phospha-Michael Reaction: Ultrafast Double Addition of P–H Bond-Bearing Nucleophiles to Electron-Deficient Triple Bonds and Its Use for Functional …

G Sagdic, O Daglar, E Cakmakci, V Findik… - …, 2023 - ACS Publications
In this work, a novel, straightforward, robust, fast, and organocatalyst-mediated phospha-
Michael reaction (OCPMR) was developed for the addition of phosphorus nucleophiles to …

[HTML][HTML] Coumarin-DPPO a new bio-based phosphorus additive for poly (lactic acid): Processing and flame retardant application

D Roncucci, MO Augé, S Dul, J Chen… - Polymer Degradation …, 2024 - Elsevier
This study addresses very important aspects of the sustainable development of new flame
retardant materials:(i) the preparation of a novel flame retardant (FR) additive from bio …

Tailored Bisacylphosphane Oxides for Precise Induction of Oxidative Stress-Mediated Cell Death in Biological Systems

K Almahayni, JB Salvador, R Conti, A Widera… - ACS Chemical …, 2024 - ACS Publications
Precise cell elimination within intricate cellular populations is hampered by issues arising
from the multifaceted biological properties of cells and the expansive reactivity of chemical …

A Genuine Trivalent Bis‐Acylphosphide (BAP) Complex of Uranium

J Hochholzer, P Waldschmidt… - European Journal of …, 2024 - Wiley Online Library
The genuine trivalent uranium complex, K [UIII (mesBAP) 4], employing four bidentate bis (2,
4, 6‐trimethylbenzoyl) phosphide (mesBAP) chelating ligands, is reported and obtained by …

A quest for stable phosphonyl radicals: limitations and possibilities of carbocyclic backbones and bulky substituents

P Kaymak, M Yang, Z Benkő - Dalton Transactions, 2023 - pubs.rsc.org
Although phosphonyl radicals play an important role as transient species in many chemical
transformations, such as photoinitiated polymerisation reactions, permanently stable …

A Simple Manganese(I) Catalyst for the Efficient and Selective Hydrophosphination of Olefins with PH3, Primary, and Secondary Phosphanes

AA Wani, JJG Carballo, H Jayaprakash… - … A European Journal, 2024 - Wiley Online Library
A tridentate ligand L with a P, NH, N donor motif was synthesized in few steps from
commercially available precursors. Upon reaction with [MnBr (CO) 5], an octahedral 18 …

Introducing the Bis (mesitoyl) phosphide Ligand into Dinuclear Trivalent Rare Earth Metal Coordination Chemistry

S Deshapriya, F Delano IV, S Demir - ChemPlusChem, 2024 - Wiley Online Library
Anionic ancillary ligands play a critical role in the construction of rare earth (RE) metal
complexes due to the large influence on the stability of the molecule and engendering …

Cyclo‐Bis (Acyl) phosphine Oxides as Efficient Photoinitiators for Radical Polymerization

Z Peng, Q Shen, X Chen - European Journal of Inorganic …, 2024 - Wiley Online Library
Acyclic acylphosphine oxides have been extensively utilized in industrial applications as
typical photoinitiators (PIs). In this study, we demonstrate the efficiency of their cyclic …

Silver-catalyzed radical bisphosphonation reaction of maleimides with diarylphosphine oxides

W Zhang, HL Ruan, ZJ Zhu, SY Zhao - Tetrahedron Letters, 2023 - Elsevier
A silver-catalyzed bisphosphonate reaction of substituted maleimides with various
diarylphosphine oxides was developed. This methodology provided an efficient strategy to …

Trendbericht Anorganik 2024: Hauptgruppen‐und Molekülchemie

M Fischer, D Heift - Nachrichten aus der Chemie, 2024 - Wiley Online Library
Hauptgruppen‐und Molekülchemie: Die leichteste Metall‐Metall‐Bindung im Bisberyllocen;
ein doppeltes Highlight in der Carbenchemie: C zweifach oxidiert mit formal vier …