Recent progress in the science of complex coacervation

CE Sing, SL Perry - Soft Matter, 2020 - pubs.rsc.org
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …

Polymer complex fiber: Property, functionality, and applications

H Huang, M Trentle, Z Liu, K Xiang… - … Applied Materials & …, 2023 - ACS Publications
Polymer complex fibers (PCFs) are a novel kind of fiber material processed from polymer
complexes that are assembled through noncovalent interactions. These can realize the …

An overview of coacervates: The special disperse state of amphiphilic and polymeric materials in solution

SP Moulik, AK Rakshit, A Pan, B Naskar - Colloids and Interfaces, 2022 - mdpi.com
Individual amphiphiles, polymers, and colloidal dispersions influenced by temperature, pH,
and environmental conditions or interactions between their oppositely charged pairs in …

Effect of polymer chemistry on the linear viscoelasticity of complex coacervates

Y Liu, CF Santa Chalarca, RN Carmean… - …, 2020 - ACS Publications
Complex coacervates can form through the electrostatic complexation of oppositely charged
polymers. The material properties of the resulting coacervates can change based on the …

Emerging trends in the dynamics of polyelectrolyte complexes

SM Lalwani, CI Eneh, JL Lutkenhaus - Physical Chemistry Chemical …, 2020 - pubs.rsc.org
Polyelectrolyte complexes (PECs) are highly tunable materials that result from the phase
separation that occurs upon mixing oppositely charged polymers. Over the years, they have …

Moderated ionic bonding for water-free recyclable polyelectrolyte complex materials

SGM van Lange, DW Te Brake, G Portale… - Science …, 2024 - science.org
While nature extensively uses electrostatic bonding between oppositely charged polymers
to assemble and stabilize materials, harnessing these interactions in synthetic systems has …

Salt-induced liquid–liquid phase separation: Combined experimental and theoretical investigation of water–acetonitrile–salt mixtures

M Li, B Zhuang, Y Lu, L An… - Journal of the American …, 2021 - ACS Publications
Salt-induced liquid–liquid phase separation in liquid mixtures is a common phenomenon in
nature and in various applications, such as in separation and extraction of chemicals. Here …

Influence of nonstoichiometry on the viscoelastic properties of a polyelectrolyte complex

Y Chen, M Yang, SA Shaheen, JB Schlenoff - Macromolecules, 2021 - ACS Publications
Depending on conditions such as the mixing ratio, speed and order of addition, and ionic
strength, when solutions of oppositely charged polyelectrolytes are mixed, the stoichiometry …

Solid-to-liquid phase transition in polyelectrolyte complexes

S Meng, JM Ting, H Wu, MV Tirrell - Macromolecules, 2020 - ACS Publications
Strongly interacting polyelectrolyte complexes (PECs) are known to form solid precipitates
that can transform into liquid droplets upon the addition of salt to break intrinsic ionic …

Behavior of supramolecular cross-links formed by host-guest interactions in hydrogels responding to water contents

C Ueda, J Park, K Hirose, S Konishi, Y Ikemoto… - Supramolecular …, 2022 - Elsevier
Reversible or movable cross-links based on host-guest interactions in supramolecular
materials create functions such as enhanced mechanical properties and stimulus …