Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Importance of size and contact structure of gold nanoparticles for the genesis of unique catalytic processes

T Ishida, T Murayama, A Taketoshi, M Haruta - Chemical reviews, 2019 - ACS Publications
Since the discovery of catalysis by Au nanoparticles (NPs), unique catalytic features of Au
have appeared that are greatly different from those of Pd and Pt. In this Review, we aimed to …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Direct propylene epoxidation with oxygen using a photo-electro-heterogeneous catalytic system

M Ko, Y Kim, J Woo, B Lee, R Mehrotra, P Sharma… - Nature Catalysis, 2022 - nature.com
Propylene oxide is a crucial feedstock in the plastic industry. The direct epoxidation of
propylene using O2 is considered among the most promising means of producing propylene …

Catalytic applications of layered double hydroxides: recent advances and perspectives

G Fan, F Li, DG Evans, X Duan - Chemical Society Reviews, 2014 - pubs.rsc.org
This review surveys recent advances in the applications of layered double hydroxides
(LDHs) in heterogeneous catalysis. By virtue of the flexible tunability and uniform distribution …

Ag-Based nanocomposites: synthesis and applications in catalysis

G Liao, J Fang, Q Li, S Li, Z Xu, B Fang - Nanoscale, 2019 - pubs.rsc.org
Ag-Based nanocomposites, including supported Ag nanocomposites and bimetallic Ag
nanocomposites, have been intensively investigated as highly efficient catalysts because of …

Water-mediated heterogeneously catalyzed reactions

G Li, B Wang, DE Resasco - Acs Catalysis, 2019 - ACS Publications
Nature takes advantage of the pervasive presence of water to control many enzymatic
reactions by utilizing the unique properties of water, which in turn help regulating reaction …

Gold-catalyzed carbon− heteroatom bond-forming reactions

A Corma, A Leyva-Pérez, MJ Sabater - Chemical reviews, 2011 - ACS Publications
After the long-held assumption of the unreactivity of gold, numerous reactions catalyzed by
this noble metal have been increasingly emerging in the literature over the past 2 decades …

Nano-gold catalysis in fine chemical synthesis

Y Zhang, X Cui, F Shi, Y Deng - Chemical Reviews, 2012 - ACS Publications
Gold has been used for coinage, jewelry, and other arts for thousands of years due to its
stability in air. Catalytic researchers were long misled by this common sense until the …