Conspectus Lewis π acids, particularly high-valent transition metals with vacant orbitals, can
coordinate with unsaturated compounds such as alkynes and alkenes by means of π …

The polarity of a radical intermediate profoundly impacts its reactivity and selectivity. To
quantify this influence and predict its effects, the electrophilicity/nucleophilicity of> 500 …

Natural organic matter, specifically ortho-quinones organics among them, was considered
can participate in the transformation of sulfonamide antibiotics (SAs). Herein, based on …

Although photoredox catalysis is complex from a mechanistic point of view, it is also often
surprisingly efficient. In fact, the quantum efficiency of a puzzlingly large portion of …

Effective control over the crystallization of metal–organic framework (MOF) films is of great
importance not only for the performance study and optimization in related applications but …

In this study, we present a photochemical method for the amination of phenols (C–H) and
halophenols (SNAr), facilitated by dual catalytic pathways involving both Ir (III) …

Fluoroalkyl aryl ethers are valuable structural motifs in pharmaceuticals because
compounds with these motifs are more metabolically stable and more lipophilic than their …

Herein, we describe a dual photocatalytic system to synthesize phenol–pyridinium salts
using visible light. Utilizing both electron donor–acceptor (EDA) complex and iridium (III) …

The C–F bond is the strongest covalent single bond (126 kcal/mol) in carbon-centered
bonds, in which the highest electronegativity of fluorine (χ= 4) gives rise to the shortest bond …

On-surface synthesis provides tools to prepare low-dimensional supramolecular structures.
Traditionally, reactive radicals are a class of single-electron species, serving as exceptional …