The use of secondary interactions between substrates and catalysts is a promising strategy
to discover selective transition metal catalysts for atom‐economy C− H bond …

Distal C− H bond functionalization of heterocycles remained extremely challenging with
covalently attached directing groups (DG). Lack of proper site for DG attachment and …

Remote C− H functionalization of heterocyclic biaryls will be of great importance in synthesis
and medicinal chemistry. Through adjusting the geometric relationship of the directing atom …

The iridium-catalyzed C–H borylation of benzamides typically leads to meta and para
selectivities using state-of-the-art iridium-based N, N-chelating bipyridine ligands. However …

Ces dernières décennies, et inspirés des enzymes, les catalyseurs métalliques
supramoléculaires permettant la reconnaissance moléculaire par liaison hydrogène ou …