Chemistry of compounds based on 1, 2, 3-triazolylidene-type mesoionic carbenes

R Maity, B Sarkar - JACS au, 2021 - ACS Publications
Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

Application of first-row transition metal complexes bearing 1, 2, 3-triazolylidene ligands in catalysis and beyond

W Stroek, M Albrecht - Chemical Society Reviews, 2024 - pubs.rsc.org
Triazole-derived N-heterocyclic carbenes, triazolylidenes (trz) have become an interesting
alternative to the ubiquitous Arduengo-type imidazole-derived carbenes, in part because …

Azide–Alkyne “Click” Reaction in Water Using Parts-Per-Million Amine-Functionalized Azoaromatic Cu (I) Complex as Catalyst: Effect of the Amine Side Arm

M Khatua, B Goswami, Kamal, S Samanta - Inorganic Chemistry, 2021 - ACS Publications
A series of Cu (II) complexes, 1–4 and 6, were synthesized through a reaction of amine-
functionalized pincer-like ligands, HL 1, 2, L a, b, and a bidentate ligand L 1 with CuCl2 …

Metals as “Click” catalysts for alkyne-azide cycloaddition reactions: An overview

P Kalra, R Kaur, G Singh, H Singh, G Singh… - Journal of …, 2021 - Elsevier
This review emphasizes on the efficacy of various metals in their diverse oxidation states to
efficiently sew terminal alkyne to azide to give triazole ring. The emergence of Alkyne-Azide …

Highly active higher coordinated copper (i)–N-heterocyclic chalcogenone catalysed click chemistry

S Mandal, D Harijan, G Muduli… - New Journal of …, 2023 - pubs.rsc.org
The tri-coordinated and tetra-coordinated copper (I)–N-heterocyclic chalcogenone catalysed
[3+ 2] cycloaddition reaction has been reported to understand the role of ancillary ligands …

Synthesis, DFT calculations, and investigation of catalytic and biological activities of back‐bond functionalized re‐NHC‐Cu complexes

A Yagmurlu, N Buğday, Ş Yaşar… - Applied …, 2024 - Wiley Online Library
Five copper complexes (3a–e) stabilized by ring‐expanded back‐bond functionalized N‐
heterocyclic carbene ligands (re‐NHCs) were produced in the glovebox by reacting free re …

Synthesis, characterization, and evaluation of antibacterial activity of ferrocenyl‐1, 2, 3‐triazoles, triazolium salts, and triazolylidene complexes of gold (i) and silver (i)

C Hoyer, P Schwerk, L Suntrup… - European Journal of …, 2021 - Wiley Online Library
triazoles, the corresponding triazolium salts, and the resulting mesoionic carbenes (MICs) of
the 1, 2, 3‐triazol‐5‐ylidene type are at the forefront of contemporary research. In this …

Cu-catalyzed cycloaddition of aryl azides to 1-iodobuta-1, 3-diynes: an experimental and quantum chemical study of unusual regiochemistry

AI Govdi, NA Danilkina, AA Shtyrov… - New Journal of …, 2024 - pubs.rsc.org
Cu-catalyzed azide–alkyne cycloaddition (CuAAC) in the case of 1-iodoalkynes is known as
a synthetic tool towards 5-iodo-1, 2, 3-triazole derivatives. We found that CuAAC of 1 …

Copper (I)‐Catalyzed Interrupted Click Reaction: Synthesis of 1, 4, 5‐Trisubstituted 5‐Chloro‐1, 2, 3‐Triazoles

Q Wu, W Song - European Journal of Organic Chemistry, 2023 - Wiley Online Library
Halo‐1, 2, 3‐triazoles are important scaffolds in organic chemistry, but current click reactions
cannot produce 1, 4, 5‐trisubstituted 5‐chloro‐1, 2, 3‐triazoles in a simple way. Herein, we …

Combining a Low Valent Molybdenum (0) Center with a Strongly σ-Donating Mesoionic Carbene Chelate Ligand—Synthesis and Structural Characterization

BJ Elvers, P Schulan, S Pätsch, C Fischer, C Schulzke - Inorganics, 2022 - mdpi.com
Triazolylidene ligands belong to a class of N-heterocyclic carbenes of growing chemical
interest. Their precursors are readily available using Click chemistry and, therefore, highly …