K Lee, H Song, JT Park - Accounts of chemical research, 2003 - ACS Publications
[60] Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2: η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also …
The different coordination modes in fullerene organometallic complexes are reviewed. The main modes are η2 and η5, but there are some interesting studies about the other four, all of …
K Lee, ZH Choi, YJ Cho, H Song, JT Park - Organometallics, 2001 - ACS Publications
Decarbonylation of Os5 (CO) 14 (PPh3) by 2 equiv of Me3NO/CH3CN at room temperature followed by reaction with C60 in refluxing chlorobenzene produces Os5C (CO) 11 …
H Song, Y Lee, ZH Choi, K Lee, JT Park, J Kwak… - …, 2001 - ACS Publications
The reaction of C60 with Re3 (μ-H) 3 (CO) 11 (NCMe) in refluxing chlorobenzene produces Re3 (μ-H) 3 (CO) 9 (μ3-η2, η2, η2-C60)(1) in 50% yield. Initial decarbonylation of 1 with …
BK Park, CY Lee, J Jung, JH Lim… - Angewandte Chemie …, 2007 - Wiley Online Library
Considerable research effort has been devoted to preparing a variety of [60] fullerene-based (C60) derivatives because of their potential application in the optical, magnetic, electronic …
H Song, K Lee, MG Choi, JT Park - Organometallics, 2002 - ACS Publications
A new 1, 2-σ-type C60 compound, Os3 (CO) 7 (CNR)(μ3-CNR)(PPh3)(μ3-η1: η1: η2-C60)(2; R= CH2Ph), is formed from Os3 (CO) 8 (CNR)(μ3-CNR)(μ3-η1: η2: η1-C60)(1) upon …
H Song, K Lee, CH Lee, JT Park… - Angewandte Chemie …, 2001 - Wiley Online Library
Figure 1. a) Molecular structure with atomic labeling scheme for 2a. Only ipso-carbon atoms (C102 and C202) of the phenyl groups are shown for clarity. b) An expanded view of the …
H Song, CH Lee, K Lee, JT Park - Organometallics, 2002 - ACS Publications
The reaction of Os3 (CO) 9 (μ 3-η 2: η 2: η 2-C60)(1) with PhCH2N PPh3 in chlorobenzene affords the benzyl isocyanide substituted product Os3 (CO) 8 (CNR)(μ 3-η 2: η 2: η 2 …
VI Sokolov - Russian Journal of Coordination Chemistry, 2007 - Springer
Fullerenes are considered as ligands in transition metal π-complexes. The following aspects are discussed: metals able to form complexes with fullerenes; haptic numbers; homo-and …