Structural aspects of fullerene chemistry a journey through fullerene chirality
C Thilgen, F Diederich - Chemical reviews, 2006 - ACS Publications
The discovery of the fullerenes, the first molecular allotropes of carbon, in the gas phase in
19851 and the equally remarkable discovery of their synthesis in macroscopic amounts by …
19851 and the equally remarkable discovery of their synthesis in macroscopic amounts by …
[60] fullerene− metal cluster complexes: novel bonding modes and electronic communication
[60] Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2: η2:
η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also …
η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also …
Coordination modes and different hapticities for fullerene organometallic complexes
D Soto, R Salcedo - Molecules, 2012 - mdpi.com
The different coordination modes in fullerene organometallic complexes are reviewed. The
main modes are η2 and η5, but there are some interesting studies about the other four, all of …
main modes are η2 and η5, but there are some interesting studies about the other four, all of …
Reversible Interconversion between μ,η2:η2- and μ3,η2:η2:η2-C60 on a Carbido Pentaosmium Cluster Framework
Decarbonylation of Os5 (CO) 14 (PPh3) by 2 equiv of Me3NO/CH3CN at room temperature
followed by reaction with C60 in refluxing chlorobenzene produces Os5C (CO) 11 …
followed by reaction with C60 in refluxing chlorobenzene produces Os5C (CO) 11 …
Synthesis and Characterization of μ3-η2,η2,η2-C60 Trirhenium Hydrido Cluster Complexes
The reaction of C60 with Re3 (μ-H) 3 (CO) 11 (NCMe) in refluxing chlorobenzene produces
Re3 (μ-H) 3 (CO) 9 (μ3-η2, η2, η2-C60)(1) in 50% yield. Initial decarbonylation of 1 with …
Re3 (μ-H) 3 (CO) 9 (μ3-η2, η2, η2-C60)(1) in 50% yield. Initial decarbonylation of 1 with …
[Os3(CO)6(PMe3)3](μ3‐η2:η2:η2‐C60)[Re3(μ‐H)3(CO)9]: A Fullerene[60] Coordinated to Two Different Trinuclear Clusters
Considerable research effort has been devoted to preparing a variety of [60] fullerene-based
(C60) derivatives because of their potential application in the optical, magnetic, electronic …
(C60) derivatives because of their potential application in the optical, magnetic, electronic …
[60] Fullerene as a versatile four-electron donor ligand
A new 1, 2-σ-type C60 compound, Os3 (CO) 7 (CNR)(μ3-CNR)(PPh3)(μ3-η1: η1: η2-C60)(2;
R= CH2Ph), is formed from Os3 (CO) 8 (CNR)(μ3-CNR)(μ3-η1: η2: η1-C60)(1) upon …
R= CH2Ph), is formed from Os3 (CO) 8 (CNR)(μ3-CNR)(μ3-η1: η2: η1-C60)(1) upon …
First Example of the μ3‐η1,η2,η1‐C60 Bonding Mode: Ligand‐Induced Conversion of π to σ C60–Metal Complexes
Figure 1. a) Molecular structure with atomic labeling scheme for 2a. Only ipso-carbon atoms
(C102 and C202) of the phenyl groups are shown for clarity. b) An expanded view of the …
(C102 and C202) of the phenyl groups are shown for clarity. b) An expanded view of the …
Ligand-Induced Conversion of π to σ C60−Metal Cluster Complexes: Full Characterization of the μ3-η1:η2:η1-C60 Bonding Mode
The reaction of Os3 (CO) 9 (μ 3-η 2: η 2: η 2-C60)(1) with PhCH2N PPh3 in chlorobenzene
affords the benzyl isocyanide substituted product Os3 (CO) 8 (CNR)(μ 3-η 2: η 2: η 2 …
affords the benzyl isocyanide substituted product Os3 (CO) 8 (CNR)(μ 3-η 2: η 2: η 2 …
Fullerenes as a new type of ligands for transition metals
VI Sokolov - Russian Journal of Coordination Chemistry, 2007 - Springer
Fullerenes are considered as ligands in transition metal π-complexes. The following aspects
are discussed: metals able to form complexes with fullerenes; haptic numbers; homo-and …
are discussed: metals able to form complexes with fullerenes; haptic numbers; homo-and …