Application of Silver Compounds in Fluoroorganic Synthesis: A Minireview

PJ Leszczynski, MJ Jadwiszczak… - ChemistrySelect, 2023 - Wiley Online Library
The mini‐review is focused on application of silver and its compounds in fluoroorganic
synthesis, and it reflects immense progress in this field which took place during the last two …

Polymorphism of two-dimensional antiferromagnets, and

D Jezierski, W Grochala - Physical Review Materials, 2024 - APS
We present a theoretical study of relative stability, as well as of the magnetic and electronic
properties, of AgF 2 and CuF 2, in two related structural forms: orthorhombic (ambient …

Mechanochemical Synthesis and Magnetic Properties of the Mixed-Valent Binary Silver(I,II) Fluorides, AgI2AgIIF4 and AgIAgIIF3

M Belak Vivod, Z Jagličić, G King… - Journal of the …, 2024 - ACS Publications
Fluoridoargentates (II) represent a fascinating class of silver (II) compounds with structural
and magnetic similarities to cuprate superconductors. However, their synthesis is …

Strength of correlations in a silver-based cuprate analog

R Piombo, D Jezierski, HP Martins, T Jaroń… - Physical Review B, 2022 - APS
AgF 2 has been proposed as a cuprate analog, which requires strong correlation and
marked covalence. On the other hand, fluorides are usually quite ionic, and 4 d transition …

Charge doping to flat AgF 2 monolayers in a chemical capacitor setup

D Jezierski, A Grzelak, X Liu, SK Pandey… - Physical Chemistry …, 2022 - pubs.rsc.org
Flat monolayers of silver (II) fluoride, which could be obtained by epitaxial deposition on an
appropriate substrate, have been recently predicted to exhibit very strong antiferro-magnetic …

Low-temperature magnetism of

JM Wilkinson, SJ Blundell, S Biesenkamp, M Braden… - Physical Review B, 2023 - APS
KAgF 3 is a quasi-one-dimensional quantum antiferromagnet hosting a series of intriguing
structural and magnetic transitions. Here we use powder neutron diffraction, μ SR …

Charge ordering mechanism in silver difluoride

M Derzsi, K Tokár, P Piekarz, W Grochala - Physical Review B, 2022 - APS
Using density functional theory, a competition between the Mott-Hubbard and intervalence
charge transfer mechanism of electron localization is revealed in AgF 2, an important silver …

How orbitals and oxidation states determine apparent topographies in scanning tunneling microscopy: The case of fluorine on silver surfaces

AG Pueyo, JA Sánchez, I Degtev, ME Temperini… - Physical Review B, 2024 - APS
We use density functional theory calculations to characterize the early stages of fluorination
of silver's (100) and (110) surfaces. In the Ag (100) surface, the hollow site is the most …

Novel ternary Ag II Co III F 5 fluoride: synthesis, structure and magnetic characteristics

D Jezierski, Z Mazej, W Grochala - Dalton Transactions, 2024 - pubs.rsc.org
We present a new compound in the silver–cobalt-fluoride system, featuring paramagnetic
silver (d9) and high-spin cobalt (d6), synthesized by solid-state method in an autoclave …

Controlling orbital ordering of intergrowth structures with flat [Ag (II) F 2] layers to mimic oxocuprates (ii)

D Jezierski, J Lorenzana, W Grochala - Physical Chemistry Chemical …, 2025 - pubs.rsc.org
Based on density functional theory calculations, we propose a new pathway toward
compounds featuring flat [AgF2] layers which mimic [CuO2] layers in high-temperature …