The radical acylated difunctionalization of unsaturated carbon–carbon bonds, which
introduces acyl and other groups simultaneously, represents an attractive approach for the …

Radical/radical cross-coupling reactions represent an efficient and straightforward approach
for the construction of chemical bonds and accordingly have drawn increasing attention over …

There have been significant advancements in radical reactions using organocatalysts in
modern organic synthesis. Recently, NHC-catalyzed radical reactions initiated by single …

Inspired by the role of N-heterocyclic carbenes (NHCs) in natural enzymatic processes,
chemists have harnessed the umpolung (polarity reversal) reactivity of these Lewis basic …

Radical–radical coupling, the selective reaction between two different radical species, has
contributed to the methodology for connecting bulky units. Light-driven N-heterocyclic …

The carbene and photocatalyst co-catalyzed radical coupling of acyl electrophile and a
radical precursor is emerging as attractive method for ketone synthesis. However, previous …

Reactions involving allenyl ion intermediates have been widely applied in the synthesis of
functionalized allenes, but reactions involving allenyl radicals have been less studied and …

Oxidative N‐heterocyclic carbene (NHC) organocatalysis, typically leading to the formation
of acyl azolium reactive intermediates, constitutes one of the most important activation …

The development of catalyst‐controlled methods for direct functionalization of two distinct C−
H bonds represents an appealing approach for C− C formations in synthetic chemistry …

The direct functionalization of inert C (sp3)‐H bonds to form carbon‐carbon and carbon‐
heteroatom bonds offers vast potential for chemical synthesis and therefore receives …