Aliphatic polycarbonates from cyclic carbonate monomers and their application as biomaterials

W Yu, E Maynard, V Chiaradia, MC Arno… - Chemical …, 2021 - ACS Publications
Aliphatic polycarbonates have gained increased attention as biomaterials largely owing to
their biocompatibility and tunable degradation. Moreover, the ability to introduce functional …

Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Macromolecular architectures through organocatalysis

S Hu, J Zhao, G Zhang, H Schlaad - Progress in Polymer Science, 2017 - Elsevier
In virtue of the rising demand for metal-free polymeric materials, organocatalytic
polymerization has emerged and blossomed unprecedentedly in the past 15 years into an …

Polymers from sugars and CO 2: Ring-opening polymerisation and copolymerisation of cyclic carbonates derived from 2-deoxy-d-ribose

GL Gregory, G Kociok-Köhn, A Buchard - Polymer Chemistry, 2017 - pubs.rsc.org
Bio-based aliphatic polycarbonates (APCs) are attractive synthetic materials for biomedical
applications because of their biodegradabilty and biocompatability properties. A high …

Living Cationic Polymerization of ε-Caprolactone Catalyzed by a Metal-free Lewis Acid of Trityl Tetrafluoroborate

Y Xu, L Wang, C Chen, P Huang, H Dai, W Jiang… - …, 2023 - ACS Publications
Research on metal-free catalytic synthesis of polycaprolactone (PCL) is fueled by the many
practical needs for biodegradable and biocompatible materials. In this regard, the pursuit of …

En Route to CO2-Based (a)Cyclic Carbonates and Polycarbonates from Alcohols Substrates by Direct and Indirect Approaches

A Brege, B Grignard, R Méreau, C Detrembleur… - Catalysts, 2022 - mdpi.com
This review is dedicated to the state-of-the art routes used for the synthesis of CO2-based (a)
cyclic carbonates and polycarbonates from alcohol substrates, with an emphasis on their …

[HTML][HTML] 开环聚合催化剂用于脂肪族聚酯合成的研究进展

张昊天, 胡晨阳, 李莉莉, 庞烜 - 高分子学报, 2022 - gfzxb.org
与广泛使用的聚烯烃材料相比, 脂肪族聚酯由于其独特的生物相容性和可降解性, 在电子,
包装和生物医学等领域都有广泛的应用. 开环聚合(ROP) 是目前合成脂肪族聚酯的主要方法 …

Organocatalytic ring-opening copolymerization of trimethylene carbonate and dithiolane trimethylene carbonate: Impact of organocatalysts on copolymerization …

J Wei, H Meng, B Guo, Z Zhong, F Meng - Biomacromolecules, 2018 - ACS Publications
The ring opening copolymerization of trimethylene carbonate (TMC) and dithiolane
trimethylene carbonate (DTC) using acidic and basic organocatalysts, ie, diphenyl …

Sequentially bridging anionic addition and ring-opening polymerization by cooperative organocatalysis: well-defined block copolymers from methacrylates and cyclic …

M Liu, B Wang, L Pan, XH Liu, Y Li - Polymer Chemistry, 2022 - pubs.rsc.org
The organocatalytic sequential block copolymerization of dissimilar monomers with distinct
chemical characteristics is very challenging, usually involving the integration of different …

Synthesis of pH-cleavable poly (trimethylene carbonate)-based block copolymers via ROP and RAFT polymerization

J Sun, S Fransen, X Yu, D Kuckling - Polymer Chemistry, 2018 - pubs.rsc.org
In this work, poly (dimethylacrylamide)-b-poly (trimethylene carbonate)(PDMAAm-b-PTMC)
block copolymers containing a pH-sensitive imine linkage were successfully synthesized by …