The stereocontrolled introduction of vicinal heteroatomic substituents into organic molecules
is one of the most powerful ways of adding value and function. Although many methods exist …

The 3 centre‐4 electrons (3c‐4e) and the donor/acceptor or charge‐transfer models for the
description of the chemical bond in linear three‐body systems, such as I 3− and related …

The full details of mechanistic investigation on enantioselective sulfenofunctionalization of
alkenes under Lewis base catalysis are described. Solution spectroscopic identification of …

The reactions between diphenyl ditelluride,(PhTe) 2, or di (β‐naphtyl) ditelluride,(β‐
naphtylTe) 2, with equivalent amounts of iodine have been reinvestigated and the crystal …

In the crystal networks of N, N′-bis (2-chlorobenzyl)-N′′-(2, 6-difluorobenzoyl)
phosphoric triamide, C21H18Cl2F2N3O2P,(I), N-(2, 6-difluorobenzoyl)-N′, N′′-bis (4 …

Phosphines containing two N-bound pyrrolidine groups and one alkyl or aryl group have
been prepared and shown to be unusually electron rich donor ligands when compared to …

Supramolecular aggregates, driven by different molecular functionalities and crystal forces,
are studied in new phosphoramide and thiophosphoramide structures (C6H5O) 2P (O)(2 …

The structures of dimethyldichalkogenanes (H3C) 2E2 liquid at room temperature have
been determined by single-crystal x-ray diffraction {ES, α-form 1a, P21/c; Z 4; a 860.9 (5); b …

A new field of chemistry has been started with the preparation of highly unstable SCl4 in
18731 and it has developed rapidly in the last four decades. The structure of SCl4 is trigonal …

The four title compounds have been synthesized and characterized by 1H, 13C and 31P
NMR spectroscopy and their identities confirmed by elemental analysis and X-ray …