In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

Transition-metal-catalyzed C–H bond functionalization has known a rapid evolution in the
last years, offering modern strategies for reaching high molecular complexity in a step-and …

In this work, we describe a Catellani-type C–H glycosylation to provide rapid access to
various highly decorated α-C-(hetero) aryl glycosides in a modular and stereoselective …

Low valent group 14 compounds exhibit diverse structures and reactivities. The employment
of diazaborolyl anions (NHB anions), isoelectronic analogues to N-heterocyclic carbenes …

Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

C–N axially chiral skeletons are ubiquitous in bioactive natural products, pharmaceuticals,
and chiral ligands. However, their atroposelective synthesis remains a formidable challenge …

Conspectus Conversion of common reactants to diverse products is a key objective of
organic syntheses. Recent developments in transition-metal-catalyzed C–H functionalization …