Transition-metal-catalyzed C–H bond activation for the formation of C–C bonds in complex molecules

JH Docherty, TM Lister, G Mcarthur, MT Findlay… - Chemical …, 2023 - ACS Publications
Site-predictable and chemoselective C–H bond functionalization reactions offer synthetically
powerful strategies for the step-economic diversification of both feedstock and fine …

Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

U Dhawa, N Kaplaneris, L Ackermann - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …

Semi-heterogeneous photo-Cu-dual-catalytic cross-coupling reactions using polymeric carbon nitrides

Z Zhang, Y Xu, Q Zhang, S Fang, H Sun, W Ou, C Su - Science Bulletin, 2022 - Elsevier
A merger of copper catalysis and semiconductor photocatalysis using polymeric carbon
nitride (PCN) for multi-type cross-coupling reactions was developed. This dual-catalytic …

Visible-light 2, 4-dinitrophenol-mediated photoannulation of α-azidochalcones into 2, 5-diaryloxazoles

UD Newar, S Borra, RA Maurya - Organic Letters, 2022 - ACS Publications
A novel and efficient visible-light 2, 4-dinitrophenol (2, 4-DNP) mediated photoannulation of
α-azidochalcones into 2, 5-diaryloxazoles was developed. The carbon–carbon double bond …

Recent advances in visible-light-mediated functionalization of olefins and alkynes using copper catalysts

A Ramani, B Desai, BZ Dholakiya… - Chemical …, 2022 - pubs.rsc.org
Over the past decade, visible-light photoredox catalysis has blossomed as a powerful
strategy and offers a discrete activation mode complementary to thermal controlled …

Photo‐Induced Ruthenium‐Catalyzed C− H Benzylations and Allylations at Room Temperature

J Struwe, K Korvorapun, A Zangarelli… - … –A European Journal, 2021 - Wiley Online Library
The ruthenium‐catalyzed synthesis of diarylmethane compounds was realized under
exceedingly mild photoredox conditions without the use of exogenous photocatalysts. The …

Photoinduced C–H arylation of 1, 3-azoles via copper/photoredox dual catalysis

S Trienes, J Xu, L Ackermann - Chemical Science, 2024 - pubs.rsc.org
The visible light-induced C–H arylation of azoles has been accomplished by dual-catalytic
system with the aid of an inexpensive ligand-free copper (I)-catalyst in combination with a …

A heterogeneous and recoverable palladium catalyst to access the regioselective C–H alkenylation of quinoline N-oxides

D Sciosci, F Valentini, F Ferlin, S Chen, Y Gu… - Green …, 2020 - pubs.rsc.org
Herein, we disclose the first C-2-selective C–H alkenylation of quinoline N-oxides catalyzed
using a heterogeneous palladium catalyst. The protocol does not require the use of an …

Acridine Orange Hemi(Zinc Chloride) Salt as a Lewis Acid‐Photoredox Hybrid Catalyst for the Generation of α‐Carbonyl Radicals

S Das, T Mandal, S De Sarkar - Advanced Synthesis & …, 2022 - Wiley Online Library
A readily accessible organic‐inorganic hybrid catalyst is reported for the reductive
fragmentation of α‐halocarbonyl compounds. The robust hybrid catalyst is a self‐stabilizing …

A green approach for the synthesis of 2-substituted benzoxazoles and benzothiazoles via coupling/cyclization reactions

HT Nguyen, TH Nguyen, DD Pham, CT Nguyen… - Heliyon, 2021 - cell.com
We have developed the green method for the synthesis of benzoxazoles and
benzothiazoles with moderate to good yields using imidazolium chlorozincate (II) ionic liquid …