Organic free radicals are ubiquitous in chemical and biological systems. They are involved
in a huge number of fundamental processes going from simple organic reactions1-3 through …

Ionic liquids (ILs) have created their niche as a solvent of choice in the realm of synthetic
chemistry. More specifically, in polymer chemistry, these designer solvents are utilized as …

Polystyrene stars were synthesized with reversible addition–fragmentation chain‐transfer
(RAFT) polymerization. The core of the stars comprised a trithiocarbonate heptafunctional β …

In this work, new naphthoquinone‐based photoinitiators are synthesized and applied for the
first time in free radical photopolymerization. In the presence of acrylate monomers, these …

Over the past decades, organometallic complexes with precious elements, such as
ruthenium and iridium, are widely used as visible‐light photoredox catalysts. Recently, more …

Abstract Poly (2-oxazine) s (POz) have recently gained traction as a great potential for
polymeric materials with biomedical applications. Compared to polymers from its analogous …

In the last half decade, mechanoredox catalysis has enabled an entirely new genre of
polymerization methodology. In this paradigm, mechanical force, such as ultrasonic …

A methodology for kinetic modeling of atom transfer radical polymerization is developed
allowing to calculate the monomer conversion, the fraction of polymer molecules having end …

The two known Me‐and allyl‐substituted 1H‐imidazol‐3‐ium bromides 1 and 2,
respectively, were converted to the corresponding BF _4^- and BPh _4^- salts 3–6 (Scheme …

We review various methods for the photochemical grafting of organic polymers to various
substrates including, organic films, membranes, planar gold, silicon wafers, glass, silica gel …