Theory of polyelectrolytes in solutions and at surfaces

AV Dobrynin, M Rubinstein - Progress in polymer science, 2005 - Elsevier
Polyelectrolytes are polymers carrying either positively or negatively charged ionizable
groups. The properties of these polymers in solutions and at charged surfaces depend on …

Neutral and charged polymers at interfaces

RR Netz, D Andelman - Physics reports, 2003 - Elsevier
Chain-like macromolecules (polymers) show characteristic adsorption properties due to their
flexibility and internal degrees of freedom, when attracted to surfaces and interfaces. In this …

Steric effects in electrolytes: A modified Poisson-Boltzmann equation

I Borukhov, D Andelman, H Orland - Physical review letters, 1997 - APS
The adsorption of large ions from solution to a charged surface is investigated theoretically.
A generalized Poisson-Boltzmann equation which takes into account the finite size of the …

Adsorption of semiflexible polyelectrolytes on charged planar surfaces: charge compensation, charge reversal, and multilayer formation

RR Netz, JF Joanny - macromolecules, 1999 - ACS Publications
We study theoretically the adsorption of semiflexible charged polymers on an oppositely
charged flat substrate. We restrict ourselves to polymers with relatively high line charge …

Adsorption of polyelectrolytes and polyelectrolytes-surfactant mixtures at surfaces: A physico-chemical approach to a cosmetic challenge

S Llamas, E Guzman, F Ortega, N Baghdadli… - Advances in colloid and …, 2015 - Elsevier
The use of polymer and polymer-surfactant mixtures for designing and developing textile
and personal care cosmetic formulations is associated with various physico-chemical …

Formation of polyelectrolyte multilayers

M Castelnovo, JF Joanny - Langmuir, 2000 - ACS Publications
A mechanism for the formation of polyelectrolyte multilayers is proposed. All of the
experiments on such systems show that there is strong interpenetration of consecutive …

Adsorption of polyelectrolytes at oppositely charged surfaces

AV Dobrynin, A Deshkovski, M Rubinstein - Macromolecules, 2001 - ACS Publications
We have developed a scaling theory of polyelectrolyte adsorption at an oppositely charged
surface. At low surface charge densities, we predict two-dimensional adsorbed layers with …

Polyelectrolyte adsorption and charge inversion

JF Joanny - The European Physical Journal B-Condensed Matter …, 1999 - Springer
We discuss theoretically the adsorption of linear weakly charged polyelectrolyte solutions on
an oppositely charged solid surface using the classical self-consistent mean field theory. If …

Debye length and double-layer forces in polyelectrolyte solutions

R Tadmor, E Hernández-Zapata, N Chen… - …, 2002 - ACS Publications
We report experimental results and a theoretical analysis of the Debye length in aqueous
solutions of nonadsorbing polyelectrolytes. The measurements were done using a surface …

Monte Carlo study of adsorption of a polyelectrolyte onto charged surfaces

CY Kong, M Muthukumar - The Journal of chemical physics, 1998 - pubs.aip.org
By using off-lattice Monte Carlo simulations, the conditions of adsorption of a uniformly
charged polyelectrolyte onto oppositely charged planar and spherical surfaces have been …