On the Highest Oxidation States of Metal Elements in MO4 Molecules (M = Fe, Ru, Os, Hs, Sm, and Pu)

W Huang, WH Xu, WHE Schwarz, J Li - Inorganic Chemistry, 2016 - ACS Publications
Metal tetraoxygen molecules (MO4, M= Fe, Ru, Os, Hs, Sm, Pu) of all metal atoms M with
eight valence electrons are theoretically studied using density functional and correlated …

Coupled Cluster Study of the Interactions of AnO2, AnO2+, and AnO22+ (An = U, Np) with N2 and CO

R Feng, ED Glendening, KA Peterson - Inorganic Chemistry, 2020 - ACS Publications
Thermochemical and spectroscopic properties for actinyl complexes involving UO22+/1+/0
and NpO22+/1+/0 with N2 and CO, together with the UO2-O2, UO2+-O2, and UO2+-NO …

Divalent and trivalent gas-phase coordination complexes of californium: evaluating the stability of Cf (ii)

PD Dau, DK Shuh, M Sturzbecher-Hoehne… - Dalton …, 2016 - pubs.rsc.org
The divalent oxidation state is increasingly stable relative to the trivalent state for the later
actinide elements, with californium the first actinide to exhibit divalent chemistry under …

Saccharified Uranyl Ions: Self‐Assembly of UO22+ into Trinuclear Anionic Complexes by the Coordination of Glucosamine‐Derived Schiff Bases

G Schaper, M Wenzel, F Hennersdorf… - … A European Journal, 2021 - Wiley Online Library
The reaction of UO2 (OAc) 2⋅ 2H2O with the biologically inspired ligand 2‐salicylidene
glucosamine (H2L1) results in the formation of the anionic trinuclear uranyl complex [(UO2) …

Probing actinide bonds in the gas phase: theory and spectroscopy

MC Heaven, KA Peterson - Experimental and theoretical …, 2018 - Wiley Online Library
Theoretical studies of actinide compounds have two primary goals. The first is to understand
the chemical bonding within these materials and their physical properties. The second goal …