Contemporary carbocation chemistry: applications in organic synthesis

RR Naredla, DA Klumpp - Chemical reviews, 2013 - ACS Publications
Contemporary Carbocation Chemistry: Applications in Organic Synthesis | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Superacid chemistry

GA Olah, GKS Prakash, J Sommer, A Molnar - 2009 - books.google.com
The chemistry of superacids has developed in the last two decades into a field of growing
interest and importance. Now available in a new expanded second edition, this definitive …

Meldrum's acids as acylating agents in the catalytic intramolecular Friedel− Crafts reaction

E Fillion, D Fishlock, A Wilsily… - The Journal of Organic …, 2005 - ACS Publications
The intramolecular Friedel− Crafts acylation of aromatics with Meldrum's acid derivatives
catalyzed by metal trifluoromethanesulfonates is reported. Meldrum's acids are easily …

Allyl‐Palladium‐Catalyzed α, β‐Dehydrogenation of Carboxylic Acids via Enediolates

Y Zhao, Y Chen, TR Newhouse - Angewandte Chemie, 2017 - Wiley Online Library
A highly practical and step‐economic α, β‐dehydrogenation of carboxylic acids via
enediolates is reported through the use of allyl‐palladium catalysis. Dianions underwent …

Friedel-crafts-type acylation and amidation reactions in strong brønsted acid: taming superelectrophiles

A Sumita, T Ohwada - Molecules, 2022 - mdpi.com
In this review, we discuss Friedel-Crafts-type aromatic amidation and acylation reactions, not
exhaustively, but mainly based on our research results. The electrophilic species involved …

Synthesis of spirolactones and functionalized benzofurans via addition of 3-sulfonylphthalides to 2-formylaryl triflates and conversion to benzofuroisocoumarins

D Nair, P Basu, S Pati, K Baseshankar… - The Journal of …, 2023 - ACS Publications
A convenient protocol for the synthesis of spirobenzofuran-isobenzofurans and substituted
benzofurans via a modified Hauser–Kraus reaction of 3-sulfonylphthalide with 2-formylaryl …

Microwave-assisted one-pot synthesis of 1-indanones from arenes and α, β-unsaturated acyl chlorides

W Yin, Y Ma, J Xu, Y Zhao - The Journal of Organic Chemistry, 2006 - ACS Publications
Microwave-Assisted One-Pot Synthesis of 1-Indanones from Arenes and α,β-Unsaturated
Acyl Chlorides | The Journal of Organic Chemistry ACS ACS Publications C&EN CAS Find …

Alternative Reactions to Friedel-crafts Acylation on Highly Activated Substrates

DI Leite, LCF Pimentel, MCA Dias… - Current Organic …, 2024 - benthamdirect.com
Friedel-crafts acylation (FCAcyl) is the most widespread method used to prepare aryl
ketones and aldehydes. However, depending on the type of group attached to the benzene …

Synthesis of tetralone and indanone derivatives via cascade reductive Friedel–Crafts alkylation/cyclization of keto acids/esters

N Yadav, R Mahato, J Khan, H Jaiswal… - Chemical …, 2024 - pubs.rsc.org
We disclose herein a metal-free cascade reductive Friedel–Crafts alkylation/cyclization of
keto acids/esters for the synthesis of tetralones and indanones. Owing to the simple reaction …

Catalysis of photooxidation reactions through transformation between Cu 2+ and Cu+ in TiO 2–Cu–MOF composites

C Chen, T Wu, D Yang, P Zhang, H Liu… - Chemical …, 2018 - pubs.rsc.org
Novel porous TiO2@ Cu3 (BTC) 2 composites, which were synthesized using ionic liquids
(ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones …