The Impact of the Alkali Metal Ion on the Crystal Structure and (Mechano) luminescence of Terbium (III) Tetrakis (β‐diketonates)

YS Kudyakova, PA Slepukhin… - European Journal of …, 2020 - Wiley Online Library
The novel terbium (III) tetrakis (β‐diketonates) M [TbL4] with different alkali metal
counterions (Na, K, Cs) based on functionalized trifluoromethylated β‐diketonate are …

Journey of a molecule from the solid to the gas phase and vice versa: direct estimation of vapor pressure of alkaline-earth metalorganic precursors for atmospheric …

FL Presti, AL Pellegrino, G Malandrino - Dalton Transactions, 2022 - pubs.rsc.org
Atmospheric pressure (AP) vapor phase processes such as spatial atomic layer deposition
(S-ALD) and AP-metalorganic chemical vapor deposition (AP-MOCVD) are becoming …

Influence of pseudo-polymorphism on the structure and thermal behavior of the new barium β-diketonate complexes [Ba (adtfa) 2 (18-crown-6)] and [Ba (adtfa) 2 (18 …

TS Pochekutova, GK Fukin, EV Baranov, BI Petrov… - Inorganica Chimica …, 2022 - Elsevier
The new barium β-diketonate complexes with 18-crown-6 [Ba (adtfa) 2 (18-crown-6)](1) and
[Ba (adtfa) 2 (18-crown-6)](CDCl 3) 2 (2)(adtfa= 1, 1, 1-trifluoro-4-(1-adamantyl)-2, 4 …

Heterobimetallic Sodium Rare-Earth Complexes: “Third-Generation” MOCVD Precursors for the Deposition of NaREF4 (RE = Y, Gd) Films

S Battiato, P Rossi, P Paoli, G Malandrino - Inorganic Chemistry, 2018 - ACS Publications
We report the synthesis of novel heterobimetallic precursors of the formula [RE (hfa) 4]−[Na·
tetraglyme]+[RE= Y, Gd; Hhfa= 1, 1, 1, 5, 5, 5-hexafluoro-2, 4-pentanedione; tetraglyme= 2 …

Role of alkyl substituents in the structure and luminescence properties of discrete terbium (III)-lithium (I) β-diketonates

YS Kudyakova, PA Slepukhin, MS Valova… - Journal of Molecular …, 2021 - Elsevier
Functionalized perfluoroalkyl lithium β-diketonates LiL react with terbium (III) salts in
methanol to give heterobimetallic complexes of general formula [(TbL 3)(LiL)(MeOH)]. The …

A One‐Pot Synthesis of “K (hfa) glyme” Adducts: Effect of the Polyether Length on the Ion Coordination Sphere

N Peddagopu, S Sanzaro, P Rossi… - European Journal of …, 2021 - Wiley Online Library
Potassium complexes are starting to gather more and more interest from academia and
industry because of their intriguing application possibilities. Novel adducts of potassium …

Extraction of Mixed-Ligand Complex Compounds of Europium (III) with β-Diketones and Carboxylic Acids in the Presence of Tris-(hydroxymethyl)-aminomethane

NI Steblevskaya - Theoretical Foundations of Chemical Engineering, 2022 - Springer
The extraction of complex compounds of europium (III) with β-diketones—acetylacetone and
dibenzoylmethane—in the presence of acetic and trifluoroacetic carboxylic acid, including …

Thermodynamic Study of a Volatile Complex of Magnesium Benzoyltrifluoroacetonate with N,N,N',N'-Tetramethylethylenediamine

ES Vikulova, SV Sysoev, AV Sartakova… - Russian Journal of …, 2023 - Springer
To expand the library of volatile magnesium precursors certified for effective use in chemical
gas-phase deposition of the corresponding oxide or fluoride layers, a thermodynamic study …

STRUCTURE OF MIXED-LIGAND MAGNESIUM DIPIVALOYLMETHANATE COMPLEXES WITH PROPYLENEDIAMINE AND ITS DERIVATIVE

ES Vikulova, EA Rikhter, DA Piryazev… - Journal of Structural …, 2020 - Springer
The structures of two mixed-ligand [Mg (Q)(thd) 2] complexes (thd= 2, 2, 6, 6-
tetramethylheptane-3, 5-dionate ion (dipivaloylmethanate ion), Q= propane-1, 3-diamine …

Термодинамическое исследование летучего комплекса бензоилтрифторацетоната магния с N, N, N', N'-тетраметилэтилендиамином

ЕС Викулова, СВ Сысоев… - Žurnal …, 2023 - journals.rcsi.science
Для расширения библиотеки летучих прекурсоров магния, аттестованных для
эффективного применения в химических газофазных процессах осаждения …