Borophene synthesis on Au (111)

B Kiraly, X Liu, L Wang, Z Zhang, AJ Mannix… - ACS …, 2019 - ACS Publications
Borophene (the first two-dimensional (2D) allotrope of boron) is emerging as a
groundbreaking system for boron-based chemistry and, more broadly, the field of low …

Bimetallic PtFe-catalyzed selective hydrogenation of furfural to furfuryl alcohol: solvent effect of isopropanol and hydrogen activation

X Gao, S Tian, Y Jin, X Wan, C Zhou… - ACS sustainable …, 2020 - ACS Publications
Highly selective liquid-phase hydrogenation of furfural was efficiently catalyzed by PtFe alloy
nanoparticles supported on CeO2. An initial reaction rate at∼ 1500 h–1, a near 100 …

[HTML][HTML] Recent advances in the use of curved single crystal surfaces

SV Auras, LBF Juurlink - Progress in Surface Science, 2021 - Elsevier
In surface science, research traditionally employs macroscopically flat surfaces of single
crystals. Curved surfaces have been applied more sporadically, but their history stretches …

Iron as modifier of Pd and Pt-based catalysts for sustainable and green processes

S Capelli, S Cattaneo, M Stucchi, A Villa, L Prati - Inorganica Chimica Acta, 2022 - Elsevier
This review provides an overview of the synthetic methods used for the preparation of
monometallic Pd and Pt metal nanoparticles (NPs) supported on iron oxide and bimetallic …

Atomic-scale identification of the electrochemical roughening of platinum

L Jacobse, MJ Rost, MTM Koper - ACS central science, 2019 - ACS Publications
Electrode degradation under oxidizing conditions is a major drawback for large-scale
applications of platinum electrocatalysts. Subjecting Pt (111) to oxidation–reduction cycles is …

Site-specific reactivity of molecules with surface defects—the case of H2 dissociation on Pt

R Van Lent, SV Auras, K Cao, AJ Walsh, MA Gleeson… - Science, 2019 - science.org
The classic system that describes weakly activated dissociation in heterogeneous catalysis
has been explained by two dynamical models that are fundamentally at odds. Whereas one …

Towards bridging the structure gap in heterogeneous catalysis: the impact of defects in dissociative chemisorption of methane on Ir surfaces

X Zhou, Y Zhang, H Guo, B Jiang - Physical Chemistry Chemical …, 2021 - pubs.rsc.org
A quantitative understanding of the role played by defect sites in heterogeneous catalysis is
of great importance in designing new and more effective catalysts. In this work, we report a …

[HTML][HTML] Revealing CO2 dissociation pathways at vicinal copper (997) interfaces

J Kim, Y Yu, TW Go, JJ Gallet, F Bournel… - Nature …, 2023 - nature.com
Size-and shape-tailored copper (Cu) nanocrystals can offer vicinal planes for facile carbon
dioxide (CO2) activation. Despite extensive reactivity benchmarks, a correlation between …

Nature of support plays vital roles in H2O promoted CO oxidation over Pt catalysts

Y Hu, X Liu, Y Zou, H Xie, T Zhu - Journal of Catalysis, 2022 - Elsevier
Pt nanoparticle catalysts supported on a series of TiO 2-SiO 2 composites with different
molar ratios were prepared, characterized, and their CO oxidation activities were evaluated …

Catalytic oxidation of carbon monoxide on a curved Pd crystal: spatial variation of active and poisoning phases in stationary conditions

F Schiller, M Ilyn, V Pérez-Dieste… - Journal of the …, 2018 - ACS Publications
Understanding nanoparticle catalysis requires novel approaches in which adjoining crystal
orientations can be studied under the same reactive conditions. Here we use a curved …