Surface chemistry and catalysis confined under two-dimensional materials

Q Fu, X Bao - Chemical Society Reviews, 2017 - pubs.rsc.org
Two-dimensional (2D) materials are characterised by their strong intraplanar bonding but
weak interplanar interaction. Interfaces between neighboring 2D layers or between 2D …

The necessity of structural irregularities for the chemical applications of graphene

A Eftekhari, H Garcia - Materials Today Chemistry, 2017 - Elsevier
Graphene is a fashionable material in the realm of nanotechnology, but its potentials are
somehow misunderstood. Although a defect-free flat graphene looks perfect with …

Confined catalysis under two-dimensional materials

H Li, J Xiao, Q Fu, X Bao - Proceedings of the National …, 2017 - National Acad Sciences
Confined microenvironments formed in heterogeneous catalysts have recently been
recognized as equally important as catalytically active sites. Understanding the …

Synthesis, properties and potential applications of hydrogenated graphene

Y Fei, S Fang, YH Hu - Chemical Engineering Journal, 2020 - Elsevier
Graphene-based materials have attracted considerable attentions due to their unique
properties. However, the negligible and uncontrollable band gap of graphene greatly limits …

State of the surface during CO hydrogenation over Ni (111) and Ni (211) probed by operando X-ray photoelectron spectroscopy

D Degerman, P Lömker, CM Goodwin… - The Journal of …, 2023 - ACS Publications
The state of the surface near-region during CO hydrogenation of Ni (111) and Ni (211)
single crystal surfaces was investigated using various gas mixtures between 150 and 500 …

Spin-triplet excitonic insulator: The case of semihydrogenated graphene

Z Jiang, W Lou, Y Liu, Y Li, H Song, K Chang… - Physical Review Letters, 2020 - APS
While various excitonic insulators have been studied in the literature, due to the perceived
too-small spin splitting, spin-triplet excitonic insulator is rare. In two-dimensional systems …

Phononic hybrid-order topology in semihydrogenated graphene

W Liu, ZK Ding, N Luo, J Zeng, LM Tang, KQ Chen - Physical Review B, 2024 - APS
In recent years, first-order and second-order topological phonons have been discovered in
crystalline materials, which has aroused great interest. In the present work, through …

Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene

R Papadakis, H Li, J Bergman, A Lundstedt… - Nature …, 2016 - nature.com
The first hydrogenation step of benzene, which is endergonic in the electronic ground state
(S0), becomes exergonic in the first triplet state (T1). This is in line with Baird's rule, which …

Topological and quantum stability of low-dimensional crystalline lattices with multiple nonequivalent sublattices

PV Avramov, AV Kuklin - New Journal of Physics, 2022 - iopscience.iop.org
The terms of topological and quantum stabilities of low-dimensional crystalline carbon
lattices with multiple non-equivalent sublattices are coined using theoretical analysis …

Unveiling the Mechanisms Leading to H2 Production Promoted by Water Decomposition on Epitaxial Graphene at Room Temperature

A Politano, M Cattelan, DW Boukhvalov, D Campi… - Acs Nano, 2016 - ACS Publications
By means of a combination of surface-science spectroscopies and theory, we investigate the
mechanisms ruling the catalytic role of epitaxial graphene (Gr) grown on transition-metal …