Stimuli-responsive metal–ligand assemblies

AJ McConnell, CS Wood, PP Neelakandan… - Chemical …, 2015 - ACS Publications
Within living systems, molecular-scale responses to stimuli flow together into the intricate
and robust signal transduction networks that process information for an organism. Studies of …

Metals, macrocycles and molecular assemblies–macrocyclic complexes in metallo-supramolecular chemistry

LF Lindoy, KM Park, SS Lee - Chemical Society Reviews, 2013 - pubs.rsc.org
In this tutorial review the use of macrocyclic complexes as building blocks in a selection of
supramolecular systems is discussed with emphasis on the properties, such as enhanced …

Mechanistic insight into organic and catalytic reactions by joint studies using mass spectrometry and NMR spectroscopy

PA Belyakov, VI Kadentsev, AO Chizhov… - Mendeleev …, 2010 - Elsevier
Utilization of NMR spectroscopy and mass spectrometry for joint mechanistic and structural
studies is a well-known practice. Several opportunities have appeared in recent years …

Heterometallic supramolecular polymers: From synthesis to properties and applications

MK Bera, S Sarmah, DC Santra, M Higuchi - Coordination Chemistry …, 2024 - Elsevier
Heterometallic supramolecular polymers (HMSPs) comprising two or more heterometal ions
have drawn significant research interest in the last two decades because of their attractive …

Novel supramolecular thixotropic metallohydrogels consisting of rare metal–organic nanoparticles: synthesis, characterization, and mechanism of aggregation

W Fang, Z Sun, T Tu - The Journal of Physical Chemistry C, 2013 - ACS Publications
Even without obvious sticky sites, novel supramolecular thixotropic metallohydrogels
consisting of rare metal–organic nanoparticles (MNPs) have been readily accessible from …

Metallo-supramolecular gels based on a multitopic cyclam bis-terpyridine platform

A Gasnier, G Royal, P Terech - Langmuir, 2009 - ACS Publications
The domain of soluble metallopolymers (ie, polymers spontaneously obtained from the self-
assembly of metal ions and polytopic bridging ligands) is promising for the construction of …

Characterization of strain recovery and “self-healing” in a self-assembled metallo-gel

P Terech, M Yan, M Maréchal, G Royal… - Physical Chemistry …, 2013 - pubs.rsc.org
We report a self-assembled metallo suprapolymer gel exhibiting remarkable self-healing
features. The Ni2BTC metallo suprapolymer gels result from the complexation of Ni2+ metal …

Redox‐Triggered Folding of Self‐Assembled Coordination Polymers incorporating Viologen Units

WS Abdul‐Hassan, D Roux, C Bucher… - … A European Journal, 2018 - Wiley Online Library
We report the study of stimuli‐responsive ZnII and FeII coordination polymers (MC34+ or
MC24+ with M= Fe2+ or Zn2+). These soluble metallopolymers were formed spontaneously …

Redox-induced polymerisation/depolymerisation of metallo-supramolecular polymers

AK Miller, Z Li, KA Streletzky, AM Jamieson… - Polymer …, 2012 - pubs.rsc.org
Redox-responsive metallo-supramolecular polymers (MSPs), consisting of a ditopic ligand
end-capped poly (tetrahydrofuran)(pTHF) macromonomer self-assembled with copper ions …

Redox-responsive colloidal particles based on coordination polymers incorporating viologen units

J Courtois, B Wang, WS Abdul-Hassan… - Inorganic …, 2020 - ACS Publications
Colloidal particles based on supramolecular polymers are emerging as promising functional
materials because of their intrinsic dynamic features and the possibility of stimuli …