The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

This review covers the advance in the development of Fe, Co, and Ni catalysts for the alkene
hydrosilylation reaction, as well as the related dehydrogenative silylation reaction. The …

Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …

One of the most challenging tasks in organic synthesis is to control selectivities, especially
switching the well-known selectivity to obtain new isomers that were previously inaccessible …

Although there has been significant progress in the development of transition‐metal‐
catalyzed hydrosilylations of alkenes over the past several decades, metal‐free …