Borates: A rich source for optical materials

M Mutailipu, KR Poeppelmeier, S Pan - Chemical Reviews, 2020 - ACS Publications
The primary goal of this review is to present a clear chemical perspective of borates in order
to stimulate and facilitate the discovery of new borate-based optical materials. These …

Targeting the next generation of deep-ultraviolet nonlinear optical materials: expanding from borates to borate fluorides to fluorooxoborates

M Mutailipu, M Zhang, Z Yang… - Accounts of Chemical …, 2019 - ACS Publications
Conspectus Coherent light radiation down to the deep-ultraviolet spectral range (λ< 200 nm)
produced by common laser sources is extensively used in diverse fields ranging from …

Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2

M Mutailipu, F Li, C Jin, Z Yang… - Angewandte Chemie …, 2022 - Wiley Online Library
Discovery of new efficient nonlinear optical (NLO) materials with large second‐order
nonlinearity for the short‐wave ultraviolet spectral region (λPM≤ 266 nm, PM= phase …

Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters

C Jin, F Li, B Cheng, H Qiu, Z Yang, S Pan… - Angewandte …, 2022 - Wiley Online Library
Polarization modulation of deep‐UV light is of significance to current technologies, and to
this end, the birefringent crystal has emerged as an invaluable material as it allows for …

Fluorination Strategy Towards Symmetry Breaking of Boron‐centered Tetrahedron for Poly‐fluorinated Optical Crystals

H Qiu, F Li, C Jin, Z Yang, J Li, S Pan… - Angewandte …, 2024 - Wiley Online Library
Borate crystals can be chemically and functionally modified by the fluorination strategy,
which encourages the identification of emerging fluorooxoborates with a structure and set of …

Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application

M Xia, F Li, M Mutailipu, S Han, Z Yang… - Angewandte …, 2021 - Wiley Online Library
The generated light can be tuned to cover almost the entire spectral range from deep‐
ultraviolet to terahertz wavelengths by utilizing the nonlinear optical crystals with a simple …

Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

C Jin, X Shi, H Zeng, S Han, Z Chen… - Angewandte Chemie …, 2021 - Wiley Online Library
Maximizing the optical anisotropy in birefringent materials has emerged as an efficient route
for modulating the polarization‐dependent light propagation. Currently, the generation of …

Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template

Z Li, W Jin, F Zhang, Z Yang, S Pan - ACS Central Science, 2022 - ACS Publications
Exploration of nonlinear optical (NLO) crystals that are competent in generating short-
wavelength ultraviolet (UV, λ≤ 266 nm, and even deep-UV, λ≤ 200 nm) coherent light …

Fluorine‐driven enhancement of birefringence in the fluorooxosulfate: a deep evaluation from a joint experimental and computational study

W Jin, W Zhang, A Tudi, L Wang, X Zhou… - Advanced …, 2021 - Wiley Online Library
Understanding and exploring the functional modules (FMs) consisting of local atomic groups
can promote the development of the materials with functional performances. Oxygen …

Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

Z Li, W Jin, F Zhang, Z Chen, Z Yang… - Angewandte …, 2022 - Wiley Online Library
Ultraviolet (UV) nonlinear optical (NLO) crystals which can produce short‐wavelength lasers
via a direct second harmonic generation (SHG) process are of great importance in modern …