A single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …

Pyrazolines are important five‐membered heterocycles, containing two adjacent nitrogen
atoms. They can incorporate various functional groups and possess unique biological …

Cross‐coupling of nitriles and alcohols offers an environmentally friendly and atom‐
economical method for the synthesis of various valuable compounds. These compounds …

The synthesis of mono‐N‐methylated aliphatic primary amines has traditionally been
challenging, requiring noble metal catalysts and high‐pressure H2 for achieving satisfactory …

Methods for the synthesis of α-branched alkylamines are important due to their ubiquity in
biologically active molecules. Despite the development of many methods for amine …

Borrowing hydrogen (BH) reactions are very useful for the sustainable synthesis of C− C and
C− N bonds. They generally operate with transition metal‐based catalysts along with …

Here we designed and synthesized a NN–CoII bidentate complex and efficiently used it for
general and expedient amination of alcohols under benign, solventless conditions. Both …

Herein, we report the catalytic application of new orthometallated palladium (II) C^ N^ S
pincer complexes (Pd1–Pd3) for the sustainable and cost-effective synthesis of …

N-alkylated piperazines can be synthesized by the thermal catalytic alkylation of piperazine
with alkyl halides or alcohols in the presence of supported metal catalysts. However, these …

Herein, we report an iron-catalyzed transfer hydrogenation of allylic alcohols. The
operationally simple protocol employs a well-defined bench stable (cyclopentadienone) iron …