At the advent of cross-coupling chemistry, carbon electrophiles based on halides or
pseudohalides were the only suitable electrophilic coupling partners. Almost two decades …

Transition‐metal‐catalyzed electrophilic amination has been developed into a powerful tool
for C− N bond construction. So far, O‐benzoylhydroxylamines are the most widely used …

A copper-catalyzed amino lactonization of unsaturated carboxylic acids has been achieved
as well as the analogous intermolecular three-component amino oxygenation of olefins. The …

Conspectus Metalloles are derivatives of cyclopentadiene in which the methylene unit is
replaced by a heteroatom, such as S, Se, Te, N, P, As, Sb, Bi, Si, Ge, Sn, B, Al, Ga, and so …

Electrophilic nitrogen sources are an increasingly popular class of reagents for the formation
of C–N bonds. Recently, a significant number of useful methodologies have been reported …

The preparation of unsaturated secondary lactams via the palladium-catalyzed cyclization of
O-phenyl hydroxamates onto a pendent alkene is reported. This method provides rapid …

Direct amination of heteroarenes and arenes has been achieved in a one‐pot C H
zincation/copper‐catalyzed electrophilic amination procedure. This amination method …

Copper-catalyzed coupling reactions have been recognized as one of the most useful
strategies for the formation of C–N bonds. This perspective gives an overview of the recent …

Despite significant recent progress in copper‐catalyzed enantioselective hydroamination
chemistry, the synthesis of chiral N‐arylamines, which are frequently found in natural …

Tertiary amides are efficiently reduced to their corresponding enamines under
hydrosilylation conditions, using a transition-metal-free catalytic protocol based on t-BuOK (5 …