Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Ligand development for copper-catalyzed enantioconvergent radical cross-coupling of racemic alkyl halides

XY Dong, ZL Li, QS Gu, XY Liu - Journal of the American Chemical …, 2022 - ACS Publications
The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

Direct Synthesis of Sulfonamides via Synergetic Photoredox and Copper Catalysis

M Zhang, L Liu, B Wang, Y Yang, Y Liu, Z Wang… - ACS …, 2023 - ACS Publications
Despite the frequent occurrence of sulfonamides in contemporary pharmaceuticals and
agrochemicals, the synthesis of these compounds is limited by the availability of preexisting …

Photocatalyzed Enantioselective Functionalization of C(sp3)–H Bonds

GQ Xu, WD Wang, PF Xu - Journal of the American Chemical …, 2024 - ACS Publications
Owing to its diverse activation processes including single-electron transfer (SET) and
hydrogen-atom transfer (HAT), visible-light photocatalysis has emerged as a sustainable …

Recent progress of Cu-catalyzed azide-alkyne cycloaddition reactions (CuAAC) in sustainable solvents: Glycerol, deep eutectic solvents, and aqueous media

N Nebra, J García-Álvarez - Molecules, 2020 - mdpi.com
This mini-review presents a general overview of the progress achieved during the last
decade on the amalgamation of CuAAC processes (copper-catalyzed azide-alkyne …

Well-defined organometallic Copper (III) complexes: Preparation, characterization and reactivity

H Liu, Q Shen - Coordination Chemistry Reviews, 2021 - Elsevier
Organocopper (III) species were generally considered as the key intermediates in a variety
of copper-catalyzed cross-coupling reactions, aerobic oxidations, as well as enzyme …

Sustainable Wacker‐Type Oxidations

P Rajeshwaran, J Trouvé, K Youssef… - Angewandte Chemie …, 2022 - Wiley Online Library
The Wacker reaction is the oxidation of olefins to ketones and typically requires expensive
and scarce palladium catalysts in the presence of an additional copper co‐catalyst under …

Copper-catalyzed hydroformylation and hydroxymethylation of styrenes

HQ Geng, T Meyer, R Franke, XF Wu - Chemical Science, 2021 - pubs.rsc.org
Hydroformylation catalyzed by transition metals is one of the most important homogeneously
catalyzed reactions in industrial organic chemistry. Millions of tons of aldehydes and related …

Waste-derived copper flakes for solvent-free reductive acetamidation of nitroarenes

NK Lamba, P Choudhary, Twinkle, J Kaushik… - Langmuir, 2024 - ACS Publications
Herein, waste-derived copper (Cu) flakes have been used as heterogeneous catalysts for
the solvent-free and one-pot reductive acetamidation of nitroarenes. Metallic copper flakes (f …

Azide–Alkyne Cycloaddition Catalyzed by Copper (I) Coordination Polymers in PPM Levels Using Deep Eutectic Solvents as Reusable Reaction Media: A Waste …

S Sethi, NC Jana, S Behera, RR Behera, B Bagh - ACS omega, 2022 - ACS Publications
Two air-stable copper (I)–halide coordination polymers 1 and 2 with NNS and NNO ligand
frameworks were synthesized and successfully utilized as efficient catalysts in an important …