Concepts and conflicts in nanoparticles reinforcement to polymers beyond hydrodynamics

Y Song, Q Zheng - Progress in Materials Science, 2016 - Elsevier
With substantial progresses in reinforcement mechanism of nanoparticle filled polymers
(NPFPs) beyond the hydrodynamic limit, now is the time to reconsider this topic …

[HTML][HTML] Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids

SK Kumar, V Ganesan, RA Riggleman - The Journal of chemical …, 2017 - pubs.aip.org
This topical review discusses the theoretical progress made in the field of polymer
nanocomposites, ie, hybrid materials created by mixing (typically inorganic) nanoparticles …

Nanocomposites with polymer grafted nanoparticles

SK Kumar, N Jouault, B Benicewicz, T Neely - Macromolecules, 2013 - ACS Publications
A recurring challenge in the field of nanocomposites is to control the spatial distribution of
nanoparticles (NPs) in a polymer matrix. This issue is of critical importance since it is now …

Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites

AP Holt, V Bocharova, S Cheng, AM Kisliuk, BT White… - ACS …, 2016 - ACS Publications
It is generally believed that the strength of the polymer–nanoparticle interaction controls the
modification of near-interface segmental mobility in polymer nanocomposites (PNCs) …

Modeling of polymer structure and conformations in polymer nanocomposites from atomistic to mesoscale: A Review

A Karatrantos, N Clarke, M Kröger - Polymer reviews, 2016 - Taylor & Francis
Over the past two decades polymer nanocomposites have received tremendous interest
from industry and academia due to their advanced properties comparative to polymer …

Effect of Interfacial Bonding on Interphase Properties in SiO2/Epoxy Nanocomposite: A Molecular Dynamics Simulation Study

Z Wang, Q Lv, S Chen, C Li, S Sun… - ACS applied materials & …, 2016 - ACS Publications
Atomistic molecular dynamics simulations have been performed to explore the effect of
interfacial bonding on the interphase properties of a nanocomposite system that consists of …

Ligand engineering of polymer nanocomposites: from the simple to the complex

Y Li, TM Krentz, L Wang, BC Benicewicz… - … applied materials & …, 2014 - ACS Publications
One key to optimizing the performance of polymer nanocomposites for high-tech
applications is surface ligand engineering of the nanofiller, which has been used to either …

A coupled MD-FE methodology to characterize mechanical interphases in polymeric nanocomposites

M Ries, G Possart, P Steinmann, S Pfaller - International Journal of …, 2021 - Elsevier
This contribution introduces an unconventional procedure to characterize spatial profiles of
elastic and inelastic properties inside polymer interphases around nanoparticles …

Chemical bond scission and physical slippage in the Mullins effect and fatigue behavior of elastomers

H Wan, K Gao, S Li, L Zhang, X Wu, X Wang… - Macromolecules, 2019 - ACS Publications
Understanding the molecular mechanism of mechanical response under a cyclic loading is
of fundamental importance in designing high-performance elastomers with a long service …

Polymer/nanoparticle interactions: bridging the gap

YN Pandey, GJ Papakonstantopoulos… - …, 2013 - ACS Publications
Materials created by dispersing nanoparticles in a polymer matrix strive to meet the promise
of enhanced and often unique properties at a reduced cost. The availability of structure …