Stabilization strategies in biomass depolymerization using chemical functionalization

YM Questell-Santiago, MV Galkin, K Barta… - Nature Reviews …, 2020 - nature.com
A central feature of most lignocellulosic-biomass-valorization strategies is the
depolymerization of all its three major constituents: cellulose and hemicellulose to simple …

Recent advances in removal of lignin from paper industry wastewater and its industrial applications–A review

I Haq, P Mazumder, AS Kalamdhad - Bioresource Technology, 2020 - Elsevier
Pulp and paper mill wastewater contains lignin related synthetic, aromatic and chlorinated
chemical compounds. Extracting lignin from pulp and paper mill wastewater is one way of …

Tunable and functional deep eutectic solvents for lignocellulose valorization

Y Liu, N Deak, Z Wang, H Yu, L Hameleers… - Nature …, 2021 - nature.com
Stabilization of reactive intermediates is an enabling concept in biomass fractionation and
depolymerization. Deep eutectic solvents (DES) are intriguing green reaction media for …

Mild organosolv lignin extraction with alcohols: the importance of benzylic alkoxylation

DS Zijlstra, CW Lahive, CA Analbers… - ACS Sustainable …, 2020 - ACS Publications
Lignin holds the key for maximizing value extraction from lignocellulosic biomass. This is
currently hindered by the application of fractionation methods that significantly alter the …

Mild organosolv pretreatment of sugarcane bagasse with acetone/phenoxyethanol/water for enhanced sugar production

W Li, X Tan, C Miao, Z Zhang, Y Wang… - Green …, 2023 - pubs.rsc.org
This study conducted mild organosolv pretreatment of sugarcane bagasse with acetone/
phenoxyethanol/water (APW) solutions to improve sugar production in the subsequent …

Deep eutectic solvent pretreatment of biomass: Influence of hydrogen bond donor and temperature on lignin extraction with high β-O-4 content

V Provost, S Dumarcay, I Ziegler-Devin… - Bioresource …, 2022 - Elsevier
Recovering lignin with high β-O-4 content is of prime interest for further high yield
depolymerization in low molecular weight phenolic compounds. Pretreatment of …

Poplar lignin structural changes during extraction in γ-valerolactone (GVL)

F Cheng, S Liu, SD Karlen, H Kim, F Lu, J Ralph… - Green …, 2023 - pubs.rsc.org
In this paper, we describe an approach for producing both high quality and high quantity of
lignin through studying the structural change of lignin during treatment of poplar wood in γ …

Lignin‐first fractionation of softwood lignocellulose using a mild dimethyl carbonate and ethylene glycol organosolv process

A De Santi, MV Galkin, CW Lahive, PJ Deuss… - …, 2020 - Wiley Online Library
A mild lignin‐first acidolysis process (140° C, 40 min) was developed using the benign
solvent dimethyl carbonate (DMC) and ethylene glycol (EG) as a stabilization agent/solvent …

Selective demethylation reactions of biomass-derived aromatic ether polymers for bio-based lignin chemicals

FM Harth, B Hočevar, TR Kozmelj… - Green …, 2023 - pubs.rsc.org
The selective demethylation of aryl methyl ethers is a reaction of high relevance both in the
context of deprotection in organic syntheses as well as in the modification of lignin and lignin …

Recent advancements in the ionic liquid mediated lignin valorization for the production of renewable materials and value-added chemicals

R Radhakrishnan, P Patra, M Das, A Ghosh - Renewable and Sustainable …, 2021 - Elsevier
Lignin is the most abundant aromatic polymer available on earth and is a recalcitrant by-
product in the lignocellulose biomass-based industry. In recent times even though about 1 g …