Solid-state NMR of quadrupolar halogen nuclei

RP Chapman, CM Widdifield, DL Bryce - Progress in Nuclear Magnetic …, 2009 - Elsevier
Chlorine, bromine, and iodine are elements of importance in a variety of inorganic and
organic compounds. For example, chlorine plays an important biological role in vital chloride …

Direct Investigation of Covalently Bound Chlorine in Organic Compounds by Solid‐State 35Cl NMR Spectroscopy and Exact Spectral Line‐Shape Simulations

FA Perras, DL Bryce - Angewandte Chemie International …, 2012 - Wiley Online Library
35/37Cl NMR spectroscopy studies of organic systems are very rare, with only a few neat
liquids having been studied.[1] The lack of chlorine NMR spectroscopy data may be …

Unravelling the structure of Magnus' pink salt

BEG Lucier, KE Johnston, W Xu… - Journal of the …, 2014 - ACS Publications
A combination of multinuclear ultra-wideline solid-state NMR, powder X-ray diffraction
(pXRD), X-ray absorption fine structure experiments, and first principles calculations of …

Solid-State 127I NMR and GIPAW DFT Study of Metal Iodides and Their Hydrates: Structure, Symmetry, and Higher-Order Quadrupole-Induced Effects

CM Widdifield, DL Bryce - The Journal of Physical Chemistry A, 2010 - ACS Publications
Central-transition 127I solid-state nuclear magnetic resonance (SSNMR) spectra are
presented for several anhydrous group 2 metal iodides (MgI2, CaI2, SrI2, and BaI2) …

Ultrafast Crystallization of AlPO4-5 Molecular Sieve in a Deep Eutectic Solvent

J Xu, Y Liu, Y Huang - The Journal of Physical Chemistry C, 2021 - ACS Publications
In the present work, ultrafast crystallization of AlPO4-5 molecular sieve was observed in a
deep eutectic solvent (DES) composed of tetraethylammonium chloride (TEACl) and …

Chlorine-35 solid-state nuclear magnetic resonance spectroscopy as an indirect probe of the oxidation number of tin in tin chlorides

BEG Lucier, VV Terskikh, J Guo, JL Bourque… - Inorganic …, 2020 - ACS Publications
Ultrawideline 35Cl solid-state nuclear magnetic resonance (SSNMR) spectra of a series of
12 tin chlorides were recorded. The magnitude of the 35Cl quadrupolar coupling constant …

Solid-State 79/81Br NMR and Gauge-Including Projector-Augmented Wave Study of Structure, Symmetry, and Hydration State in Alkaline Earth Metal Bromides

CM Widdifield, DL Bryce - The Journal of Physical Chemistry A, 2010 - ACS Publications
Bromine-79/81 solid-state NMR (SSNMR) spectroscopy is established as a tool to
characterize the local structure and symmetry about bromide ions in inorganic systems …

Probing the local structure of pure ionic liquid salts with solid‐and liquid‐state NMR

PG Gordon, DH Brouwer, JA Ripmeester - ChemPhysChem, 2010 - Wiley Online Library
Room‐temperature ionic liquids (RTILs) are gaining increasing interest and are considered
part of the green chemistry paradigm due to their negligible vapour pressure and ease of …

A Combined Solid‐State NMR and X‐ray Crystallography Study of the Bromide Ion Environments in Triphenylphosphonium Bromides

KMN Burgess, I Korobkov… - Chemistry–A European …, 2012 - Wiley Online Library
Abstract Multinuclear (31P and 79/81Br), multifield (9.4, 11.75, and 21.1 T) solid‐state
nuclear magnetic resonance experiments are performed for seven phosphonium bromides …

A multinuclear solid-state magnetic resonance and GIPAW DFT study of anhydrous calcium chloride and its hydrates

CM Widdifield, DL Bryce - Canadian Journal of Chemistry, 2011 - cdnsciencepub.com
The group 2 metal halides and corresponding metal halide hydrates serve as useful model
systems for understanding the relationship between the electric field gradient (EFG) and …