Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications

Z Li, M Tang, S Liang, M Zhang, GM Biesold… - Progress in Polymer …, 2021 - Elsevier
Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of
applications, including supersoft elastomers, organic optoelectronics, templates for crafting …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Core-Clickable PEG-Branch-Azide Bivalent-Bottle-Brush Polymers by ROMP: Grafting-Through and Clicking-To

JA Johnson, YY Lu, AO Burts, YH Lim… - Journal of the …, 2011 - ACS Publications
The combination of highly efficient polymerizations with modular “click” coupling reactions
has enabled the synthesis of a wide variety of novel nanoscopic structures. Here we …

Drug-loaded, bivalent-bottle-brush polymers by graft-through ROMP

JA Johnson, YY Lu, AO Burts, Y Xia, AC Durrell… - …, 2010 - ACS Publications
Graft-through ring-opening metathesis polymerization (ROMP) using ruthenium N-
heterocyclic carbene catalysts has enabled the synthesis of bottle-brush polymers with …

Ring-opening metathesis polymerization of 8-membered cyclic olefins

H Martinez, N Ren, ME Matta, MA Hillmyer - Polymer Chemistry, 2014 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such
as the parent molecules cis-cyclooctene (COE) and cis, cis-1, 5-cyclooctadiene (COD) …

[HTML][HTML] Grubbs' and Schrock's catalysts, ring opening metathesis polymerization and molecular brushes—synthesis, characterization, properties and applications

I Choinopoulos - Polymers, 2019 - mdpi.com
In this review, molecular brushes and other macromolecular architectures bearing a
bottlebrush segment where the main chain is synthesized by ring opening metathesis …

Hyper/highly-branched polymers by radical polymerisations

RM England, S Rimmer - Polymer Chemistry, 2010 - pubs.rsc.org
Hyper branched and highly branched polymers (HB polymers) can be prepared by a variety
of radical polymerisations. Here we describe the various techniques that can be used and …

Cobalt catalysed controlled copolymerization: An efficient approach to bifunctional polyisoprene with enhanced properties

D Gong, F Tang, Y Xu, Z Hu, W Luo - Polymer Chemistry, 2021 - pubs.rsc.org
Preparation of functional polyisoprene via direct catalytic insertion polymerization has been
preferred because the polymers' regularity, molar mass and functionality can be facilely …

Amphiphilic multicomponent molecular brushes

IV Ivanov, TK Meleshko, AV Kashina… - Russian Chemical …, 2019 - iopscience.iop.org
Multicomponent molecular brushes containing amphiphilic polymer moieties are promising
objects of research of macromolecular chemistry. The development of stimulus-responsive …

Synthesis of well-defined ω-oxanorbornenyl poly (ethylene oxide) macromonomers via click chemistry and their ring-opening metathesis polymerization

D Le, V Montembault, JC Soutif… - …, 2010 - ACS Publications
ω-Oxanorbornenyl poly (ethylene oxide) monomethyl ether macromonomers were
synthesized with molecular weights ranging from 500 g/mol to 5000 g/mol through the …