Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems
M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
Synthesis and functionalization of porphyrins through organometallic methodologies
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …
through catalytic and stoichiometric organometallic methodologies. The employment of …
Heterocyclic nanographenes and other polycyclic heteroaromatic compounds: synthetic routes, properties, and applications
Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic
nanographenes) are a highly versatile class of organic materials, applicable as functional …
nanographenes) are a highly versatile class of organic materials, applicable as functional …
Conformationally restricted and ring-fused aza-BODIPYs as promising near infrared absorbing and emitting dyes
Aza-BODIPY is an important class of heteroatom-containing BODIPY analogue with strongly
electron-withdrawing nitrogen atom instead of methine carbon atom at the meso-position …
electron-withdrawing nitrogen atom instead of methine carbon atom at the meso-position …
Porphyrinoids as a platform of stable radicals
D Shimizu, A Osuka - Chemical Science, 2018 - pubs.rsc.org
The non-innocent ligand nature of porphyrins was observed for compound I in enzymatic
cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive …
cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive …
Pore confined time-of-flight secondary ion electrochemical mass spectrometry
Molecular structure conversion concomitant with mass transfer processes at the electrode–
electrolyte interfaces plays a central role in energy electrochemistry. Mass spectrometry, as …
electrolyte interfaces plays a central role in energy electrochemistry. Mass spectrometry, as …
Catalytic C–H imidation of aromatic cores of functional molecules: ligand-accelerated Cu catalysis and application to materials-and biology-oriented aromatics
T Kawakami, K Murakami, K Itami - Journal of the American …, 2015 - ACS Publications
Versatile imidation of aromatic C–H bonds was accomplished. In the presence of copper
bromide and 6, 6′-dimethyl-2, 2′-bipyridyl, a range of aromatics, such as polycyclic …
bromide and 6, 6′-dimethyl-2, 2′-bipyridyl, a range of aromatics, such as polycyclic …
Synthesis, crystal structure, and the deep near-infrared absorption/emission of bright azaBODIPY-based organic fluorophores
W Sheng, Y Wu, C Yu, P Bobadova-Parvanova… - Organic …, 2018 - ACS Publications
Annularly fused azaBODIPY-based organic fluorophores (HBPs 2) containing up to 13
aromatic ring fusions were synthesized by a Suzuki coupling reaction with …
aromatic ring fusions were synthesized by a Suzuki coupling reaction with …
Triply linked porphyrinoids
T Tanaka, A Osuka - Chemistry–A European Journal, 2018 - Wiley Online Library
Triply linked porphyrin arrays, so called porphyrin tapes, are intriguing molecules in terms of
their planar structures, far red‐shifted absorption bands, multi‐charge storage abilities, and …
their planar structures, far red‐shifted absorption bands, multi‐charge storage abilities, and …
Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations
Oxidative fusion reactions of meso-phenoxazino Ni (II) porphyrin were found to be
temperature dependent, giving rise to either a doubly phenylene-fused product at room …
temperature dependent, giving rise to either a doubly phenylene-fused product at room …