Stereospecific olefin polymerization with chiral metallocene catalysts

HH Brintzinger, D Fischer, R Mülhaupt… - … Edition in English, 1995 - Wiley Online Library
Current studies on novel, metallocenebased catalysts for the polymerization of α‐olefins
have far‐reaching implications for the development of new materials as well as for the …

Carbocyclic-fused N, N, N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization

Z Wang, GA Solan, W Zhang, WH Sun - Coordination Chemistry Reviews, 2018 - Elsevier
Recent progress in the application of homogeneous iron and cobalt catalysts in ethylene
oligo-/polymerization is reviewed with particular emphasis placed on the tuning of catalyst …

Iron and cobalt ethylene polymerization catalysts bearing 2, 6-bis (imino) pyridyl ligands: synthesis, structures, and polymerization studies

GJP Britovsek, M Bruce, VC Gibson… - Journal of the …, 1999 - ACS Publications
The synthesis, characterization, and ethylene polymerization behavior of a series of iron and
cobalt halide complexes, LMX n (M= Fe, X= Cl, n= 2, 3, X= Br, n= 2; M= Co, X= Cl, n= 2) …

New polymers by metallocene catalysis

W Kaminsky - Macromolecular Chemistry and Physics, 1996 - Wiley Online Library
Work in the field of application of metallocene‐based catalysis in olefin, diolefin and styrene
polymerization has become a research topic of growing interest in recent years. A great …

Ziegler-Natta catalysts for olefin polymerizations

K Soga, T Shiono - Progress in Polymer Science, 1997 - Elsevier
This article reviews the recent developments of Ziegler-Natta and metallocene catalysts for
olefin polymerizations. The roles of magnesium dichloride and electron donors on the …

Chemistry of Cationic Dicyclopentadienyl Group 4 Metal-Alky I Complexes

RF Jordan - Advances in organometallic chemistry, 1991 - Elsevier
Publisher Summary This chapter discusses the chemistry of cationic dicyclopentadienyl
group 4 metal–alkyl complexes. Neutral, d 0 group 4 metal alkyl complexes of general form …

Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren

HH Brintzinger, D Fischer, R Mülhaupt… - Angewandte …, 1995 - Wiley Online Library
Untersuchungen an neuen Metallocenkatalysatoren zur Polymerisation von α‐Olefinen
haben gegenwärtig weitreichende Auswirkungen auf die Entwicklung neuer Materialien und …

Metallocenes for polymer catalysis

W Kaminsky, M Arndt - Polymer Synthesis/Polymer Catalysis, 2007 - Springer
Metallocenes are very versatile catalysts for the production of polyolefins, polystyrene and
copolymers. Some polymers such as syndiotactic polypropene, syndiotactic polystyrene …

Homogeneous group 4 metallocene ziegler-natta catalysts: The influence of cyclopentadienyl-ring substituents

PC Möhring, NJ Coville - Journal of organometallic chemistry, 1994 - Elsevier
A new range of metallocene catalysts, Cp 2 MCl 2 (M= Ti, Zr, Hf) has been developed in the
past decade, which, in the presence of alumoxanes are highly efficient at polymerizing α …

Polyethylene chain growth on zinc catalyzed by olefin polymerization catalysts: a comparative investigation of highly active catalyst systems across the transition …

M Van Meurs, GJP Britovsek, VC Gibson… - Journal of the …, 2005 - ACS Publications
Highly active transition metal ethylene polymerization catalysts across the transition series
have been investigated for their ability to catalyze chain growth on zinc. In reactions of …