NHCs in main group chemistry
V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …
1990s, these divalent carbon species have become a common and available class of …
Small inorganic rings in the 21st century: From fleeting intermediates to novel isolable entities
Cyclic structures represent a well-studied structural class due to the novel bonding modes
and reactivity these units possess and the ubiquitous role of cyclic intermediates in a wide …
and reactivity these units possess and the ubiquitous role of cyclic intermediates in a wide …
Hydrogen abstraction from organotin di-and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin (II) species and …
CP Sindlinger, L Wesemann - Chemical Science, 2014 - pubs.rsc.org
N-Heterocyclic carbenes are shown to cleanly abstract dihydrogen from organotin di-and
trihydrides to intermediately form the reactive stannylene species [R2Sn] and [R′ SnH] …
trihydrides to intermediately form the reactive stannylene species [R2Sn] and [R′ SnH] …
N-heterocyclic carbene supported heavier group 14 elements: Recent progress and challenges
G Prabusankar, A Sathyanarayana, P Suresh… - Coordination Chemistry …, 2014 - Elsevier
N-heterocyclic carbenes have been used as potential ligands/reagents to isolate the hitherto
unknown p-block compounds with unusual structural features. The amphoteric nature of low …
unknown p-block compounds with unusual structural features. The amphoteric nature of low …
Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene
L Álvarez-Rodríguez, J Brugos, JA Cabeza… - Chemical …, 2017 - pubs.rsc.org
A PGeP pincer-type germylene, Ge (NCH2PtBu2) 2C6H4, which contains two phosphane
groups hanging from the N atoms of an N-heterocyclic germylene fragment, has been …
groups hanging from the N atoms of an N-heterocyclic germylene fragment, has been …
The transition metal chemistry of PGeP and PSnP pincer heavier tetrylenes
JA Cabeza, P García‐Álvarez… - European Journal of …, 2020 - Wiley Online Library
This review article collects and discusses the syntheses of the currently known metal‐free
heavier tetrylenes having a PEP pincer topology (E= tetrel atom) as well as their transition …
heavier tetrylenes having a PEP pincer topology (E= tetrel atom) as well as their transition …
[4‐tBu‐2,6‐{P(O)(OiPr)2}2C6H2SnL]+: An NHC‐Stabilized Organotin(II) Cation and Related Derivatives
M Wagner, T Zöller, W Hiller… - … A European Journal, 2013 - Wiley Online Library
The chemistry of stable, heavier carbene homologues is a topic of continuing interest,[1]
especially because low-valent tin cations are targets in inorganic and organometallic …
especially because low-valent tin cations are targets in inorganic and organometallic …
Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn (NCH 2 P t Bu 2) 2 C 6 H 4, attempts to prepare the PSiP analogue, and the effect …
J Brugos, JA Cabeza, P García-Álvarez… - Dalton …, 2018 - pubs.rsc.org
The non-donor-stabilized PSnP pincer-type stannylene Sn (NCH2PtBu2) 2C6H4 (1) has
been prepared by treating SnCl2 with Li2 (NCH2PtBu2) 2C6H4. All attempts to synthesize …
been prepared by treating SnCl2 with Li2 (NCH2PtBu2) 2C6H4. All attempts to synthesize …
Phosphines and related C–P bonded compounds
DW Allen - 2015 - books.rsc.org
This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …
from a few papers from 2012 in less accessible journals which came to light in Chemical …
Terphenyl Amido Stannylene‐NHC Adduct: A Catalyst for the Hydrosilylation of Aldehydes and Ketones
D Niu, JA Kelly, FJ Kiefer, A Kostenko… - … für anorganische und …, 2024 - Wiley Online Library
The terphenyl amido stannylene‐NHC adducts, HMDS (MesTer) Sn (NHC),(MesTer= 2, 6‐
Mes2C6H3, Mes= 2, 4, 6‐Me3‐C6H2, HMDS= N (SiMe3) 2, NHC= IMe4, IEt, IMe4= 1, 3, 4, 5 …
Mes2C6H3, Mes= 2, 4, 6‐Me3‐C6H2, HMDS= N (SiMe3) 2, NHC= IMe4, IEt, IMe4= 1, 3, 4, 5 …