Variable control of the electronic states of a silver nanocluster via protonation/deprotonation of polyoxometalate ligands

K Yonesato, S Yamazoe, S Kikkawa, D Yokogawa… - Chemical …, 2022 - pubs.rsc.org
The properties of metal nanoclusters depend on both their structures and electronic states.
However, in contrast to the significant advances achieved in the synthesis of structurally well …

An unprecedented oxalate-functionalized Ta/W polyoxometalate enabling the self-assembly of a 2D composite for catalytic hydrogenation

S Li, MY Huang, W Cheng, WA Shah, XS Dai… - Inorganic Chemistry …, 2024 - pubs.rsc.org
An oxalate-functionalized polyoxometalate Na2H38 [P8W60Ta12O242 (C2O4) 4]· 56H2O
(C2O4-POM) was synthesized by the reaction of the Ta/W mixed-addenda precursor …

Synthesis of photoactive Polyoxometalate-porphyrin hybrids to trigger the photocurrent by designing the ultra-thin films

U Saleem, M Tariq, M Nadeem, S Hussain, MA Khan… - Optical Materials, 2022 - Elsevier
In this work, two new, efficient, and ecofriendly hybrids based on Polyoxometalates-
porphyrin namely CuAnPOM@ 3PhP, and LPOM@ 3PhP have been synthesized and …

Photoinduced electron transfer between a noble-metal-free [Mo 6 I 8 Cl 6] 2− cluster and polyoxometalates

A Fatima, Y Smortsova, C Falaise, N Leclerc… - Chemical …, 2023 - pubs.rsc.org
Evidence for photoinduced intermolecular electron transfer from the excited state of the
[Mo6I8Cl6] 2− electron-rich cluster to polyoxometalates (POMs) is reported. We demonstrate …

Hybrid polysaccharide film infused with polyoxometalates for inkless printing and solar ultraviolet sensing

M Hussain, Z Ahmad, O Ejeromedoghene… - International Journal of …, 2025 - Elsevier
Inkless paper made from photochromic materials has garnered significant interest owing to
its potential to reduce both ink and paper pollution during production. In this research, we …

Molecular engineering and structure–property relationship based on D–A chlorophyll derivative and the application in organic solar cells

K Zhang, T Li, P Song, F Ma, Y Li - Physical Chemistry Chemical …, 2024 - pubs.rsc.org
The photoactive layer materials of organic solar cells (OSCs) play a critical role in achieving
excellent performance. Chlorophyll derivatives are commonly used due to their …

Sequential proton coupled electron transfer events from a tetraruthenium polyoxometalate in photochemical water oxidation

E Rossin, M Bonchio, M Natali… - Sustainable Energy & …, 2024 - pubs.rsc.org
The tetraruthenium polyoxometalate {RuIV (H2O) 4 (μ-OH) 2 (μ-O) 4 [SiW10O36] 2}
10−(Ru4POM) shows multiple oxidative proton coupled electron transfer (PCET) events in a …

Covalent Linkage of BODIPY‐Photosensitizers to Anderson‐Type Polyoxometalates Using CLICK Chemistry

S Cetindere, ST Clausing, M Anjass… - … A European Journal, 2021 - Wiley Online Library
The covalent attachment of molecular photosensitizers (PS) to polyoxometalates (POMs)
opens new pathways to PS‐POM dyads for light‐driven charge‐transfer and charge …

H2 Evolution at a Reduced Hybrid Polyoxometalate and Its Vanadium-Oxo Derivative Used as Molecular Models for Reducible Metal Oxides

LK/Bidi, A Desjonquères, G Izzet… - Inorganic Chemistry, 2022 - ACS Publications
We herein report our investigations on the use of a tris-silanol-decorated polyoxotungstate,[
SbW9O33 (tBuSiOH) 3] 3–, as a molecular support model to describe the coordination of an …

Synthesis of Polyoxometalates-Dianhydrides Based Polyimides for Photocurrent Generation: A Combined Experimental and Computational Study

S Arbab, A Hussain, MA Assiri, M Nadeem… - Journal of Cluster …, 2024 - Springer
Abstract New 2, 6-bis (1, 3-dihydroxy-2-(hydroxymethyl) propan-2-yl) pyrrolo [3, 4-f]
isoindole-1, 3, 5, 7 (2H, 6H)-tetraone (2Tris@ PMDA) and its polymeric hybrids with …