The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

Transition-metal-catalyzed enantioselective C–H functionalization has become a powerful
strategy for the formation of C–C or C–X bonds, enabling the highly asymmetric synthesis of …

Expanding the importance of chirality and implementation of stereogenic information within
complex molecular design has recently reached a new level: design of innovative …

The atroposelective synthesis of atropisomers with vicinal diaxes remains rare and
challenging, due to the steric influence between the two axes and their unique topology …

Catalytic dynamic kinetic asymmetric transformation (DyKAT) provides a powerful tool to
access chiral stereoisomers from racemic substrates. Such transformation has been widely …

NN axially chiral biaryls represent a rarely explored class of atropisomers. Reported herein
is construction of diverse classes of diaxially chiral biaryls containing NN and CN/CC diaxes …

Enantioselective C–H functionalization for the synthesis of chiral molecules is a challenge in
organic synthesis. Although there are several methods for atroposelective C–H …

We present herein an unprecedented stereoselective synthesis of triaryl-2-pyrones with
monoaxial or contiguous diaxes from readily available starting materials. This N-heterocyclic …

We herein demonstrated an efficient method for the atroposelective construction of nine‐
membered carbonate‐bridged biaryls through vinylidene ortho‐quinone methide (VQM) …

Atropisomers bearing multiple stereogenic axes are of increasing importance to the field of
material science, pharmaceuticals, and catalysis. However, the atroposelective construction …