Transformation networks of metal–organic cages controlled by chemical stimuli

E Benchimol, BNT Nguyen, TK Ronson… - Chemical Society …, 2022 - pubs.rsc.org
The flexibility of biomolecules enables them to adapt and transform as a result of signals
received from the external environment, expressing different functions in different contexts …

Self-Assembled Pd12 Coordination Cage as Photoregulated Oxidase-Like Nanozyme

S Bhattacharyya, SR Ali… - Journal of the …, 2020 - ACS Publications
Designing supramolecular architectures with uncommon geometries embedded with
functional building units is of immense importance in contemporary research. In this report …

Development of coordination driven self-assembled discrete spherical ensembles

NB Debata, D Tripathy, HS Sahoo - Coordination Chemistry Reviews, 2019 - Elsevier
Coordination driven self-assembly has witnessed a variety and large number of polygons as
well as polyhedra. However, the discrete larger nuclearity molecular polyhedra, which …

A Self‐Assembled Palladium (II) Barrel for Binding of Fullerenes and Photosensitization Ability of the Fullerene‐Encapsulated Barrel

PC Purba, M Maity, S Bhattacharyya… - Angewandte Chemie …, 2021 - Wiley Online Library
Fullerene extracts obtained from fullerene soot lack their real application due to their poor
solubility in common solvents and difficulty in purification. Encapsulation of these extracts in …

Self-assembled Pd (II) barrels as containers for transient merocyanine form and reverse thermochromism of spiropyran

P Howlader, B Mondal, PC Purba… - Journal of the …, 2018 - ACS Publications
Self-assembly of a cis-blocked Pd (II) 90° ditopic acceptor [cis-(tmeda) Pd (NO3) 2](M) with a
tetradentate donor L 1 [benzene-1, 4-di (4-terpyridine)] in 2: 1 molar ratio yielded two …

A Reduced‐Symmetry Heterobimetallic [PdPtL4]4+ Cage: Assembly, Guest Binding, and Stimulus‐Induced Switching

LS Lisboa, JA Findlay, LJ Wright… - Angewandte Chemie …, 2020 - Wiley Online Library
A strategy is presented that enables the quantitative assembly of a heterobimetallic [PdPtL4]
4+ cage. The presence of two different metal ions (PdII and PtII) with differing labilities …

Unusual Behavior of Donor–Acceptor Stenhouse Adducts in Confined Space of a Water-Soluble PdII8 Molecular Vessel

R Saha, A Devaraj, S Bhattacharyya… - Journal of the …, 2019 - ACS Publications
Donor–acceptor Stenhouse adducts (DASA) are new-generation photochromic compounds
discovered recently. DASA exist normally in open form (blue/violet) and readily convert to …

Rigidification-Induced Emissive Metal–Carbene Complexes for Artificial Light Harvesting

PC Purba, PK Maitra, S Bhattacharyya… - Inorganic …, 2023 - ACS Publications
A tetraphenylethylene (TPE)-based flexible imidazolium (L) salt was used to develop a di-
nuclear silver (I)–tetracarbene (1) complex. Coordination-induced rigidity upon formation of …

Silver (I)–carbene bond-directed rigidification-induced emissive metallacage for picric acid detection

PC Purba, M Venkateswaralu… - Inorganic …, 2021 - ACS Publications
A new triphenylamine-based tetraimidazolium salt L was developed for silver (I)–carbene
bond-directed synthesis of tetranuclear silver (I) octacarbene ([Ag4 (L) 2](PF6) 4) …

Coordination-assisted reversible photoswitching of spiropyran-based platinum macrocycles

S Bhattacharyya, M Maity, A Chowdhury… - Inorganic …, 2020 - ACS Publications
Control over the stimuli-responsive behavior of smart molecular systems can influence their
capability to execute complex functionalities. Herein, we report the development of a suite of …