Pilot-scale continuous synthesis of a vanadium-doped LiFePO4/C nanocomposite high-rate cathodes for lithium-ion batteries

ID Johnson, M Lübke, OY Wu, NM Makwana… - Journal of Power …, 2016 - Elsevier
A high performance vanadium-doped LiFePO 4 (LFP) electrode is synthesized using a
continuous hydrothermal method at a production rate of 6 kg per day. The supercritical water …

Magnetic and relaxation properties of vanadium (iv) complexes: an integrated 1 H relaxometric, EPR and computational study

V Lagostina, F Carniato, D Esteban-Gómez… - Inorganic Chemistry …, 2023 - pubs.rsc.org
We report a detailed study of the magnetic and relaxation properties of a series of
oxovanadium (IV) complexes comprising the aqua ion [VO (H2O) 5] 2+ and [VO (ox) 2] …

Electronic and Geometrical Structure of Zn+ Ions Stabilized in the Porous Structure of Zn-Loaded Zeolite H-ZSM-5: A Multifrequency CW and Pulse EPR Study

E Morra, G Berlier, E Borfecchia… - The Journal of …, 2017 - ACS Publications
Electron spin resonance and hyperfine sublevel correlation (HYSCORE) spectroscopy at X-
and Q-band frequencies have been employed, in conjunction with X-ray absorption …

Unraveling the Catalytic Synergy between Ti3+ and Al3+ Sites on a Chlorinated Al2O3: A Tandem Approach to Branched Polyethylene

A Piovano, KS Thushara, E Morra… - Angewandte Chemie …, 2016 - Wiley Online Library
An original step‐by‐step approach to synthesize and characterize a bifunctional
heterogeneous catalyst consisting of isolated Ti3+ centers and strong Lewis acid Al3+ sites …

Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti (III)-H in homogeneous olefin polymerization

E Salvadori, M Chiesa, A Buonerba, A Grassi - Chemical Science, 2020 - pubs.rsc.org
Metal hydride complexes find widespread application in catalysis and their properties are
often understood on the basis of the available crystal structures. However, some catalytically …

On the role and applications of electron magnetic resonance techniques in surface chemistry and heterogeneous catalysis

M Chiesa, E Giamello - Catalysis Letters, 2021 - Springer
Some relevant aspects of Electron Paramagnetic Resonance (EPR) applied to the fields of
surface chemistry and heterogeneous catalysis are illustrated in this perspective paper that …

Identification of LiPF6 Decomposition Products in Li‐Ion Batteries with Endogenous Vanadyl Sensors Using Pulse Electron Paramagnetic Resonance and Density …

C Szczuka, P Jakes, RA Eichel… - Advanced Energy and …, 2021 - Wiley Online Library
The evaluation and enhancement of Li‐ion battery chemistries relies on detailed knowledge
of the chemical processes occurring. Undesired side reactions have to be identified and …

The synthesis of Co-doped SAPO-5 molecular sieve and its performance in the oxidation of cyclohexane with molecular oxygen

Z Xiao, W Zhan, Y Guo, Y Guo, X Gong, G Lu - Chinese Journal of …, 2016 - Elsevier
Silicoaluminophosphate (SAPO) molecular sieves doped with cobalt (Co-SAPO-5) were
synthesized hydrothermally with different concentrations of Co. Each sample was …

Kinetic study of the oxovanadium(IV)–salen-catalyzed H2O2 oxidation of phenols

A Mathavan, A Ramdass, S Rajagopal - Transition Metal Chemistry, 2015 - Springer
Abstract The oxovanadium (IV)–salen-catalyzed H 2 O 2 oxidation of phenols gives o-
catechol and hydroquinone as the reaction products. The reaction follows Michaelis–Menten …

Electron paramagnetic resonance study of vanadium exchanged H-ZSM5 prepared by vapor reaction of VCl4. The role of 17O isotope labelling in the characterisation …

V Lagostina, E Salvadori, M Chiesa, E Giamello - Journal of catalysis, 2020 - Elsevier
Site isolated vanadium ions supported on zeolites are central in many catalytic processes.
However, an atomistic description of the species formed is often hampered by the …