Preparation and Post-Assembly Modification of Metallosupramolecular Assemblies from Poly(N-Heterocyclic Carbene) Ligands

MM Gan, JQ Liu, L Zhang, YY Wang, FE Hahn… - Chemical …, 2018 - ACS Publications
Although the coordination chemistry of N-heterocyclic carbenes (NHCs) with transition
metals has been explored for half a century, only in the past ten years has the chemistry of …

Complexes with poly (N-heterocyclic carbene) ligands: structural features and catalytic applications

M Poyatos, JA Mata, E Peris - Chemical reviews, 2009 - ACS Publications
The continuous growth of N-heterocyclic carbene (NHC) chemistry is a fact that is pointed
out in all the introductions of the publications regarding NHCs that have appeared in the …

Metallosupramolecular architectures obtained from poly-N-heterocyclic carbene ligands

N Sinha, FE Hahn - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus Over the past two decades, self-assembly of supramolecular architectures has
become a field of intensive research due to the wide range of applications for the resulting …

Cyclic iron tetra N-heterocyclic carbenes: synthesis, properties, reactivity, and catalysis

TP Schlachta, FE Kühn - Chemical Society Reviews, 2023 - pubs.rsc.org
Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …

Dinuclear gold (i) complexes: from bonding to applications

TACA Bayrakdar, T Scattolin, X Ma… - Chemical Society …, 2020 - pubs.rsc.org
The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …

Self-Assembly of Molecular Cylinders from Polycarbene Ligands and AgI or AuI

A Rit, T Pape, FE Hahn - Journal of the American Chemical …, 2010 - ACS Publications
Tris-and tetrakis (imidazolium) salts react with Ag2O to give cylindrical polynuclear silver (I)
complexes such as the tetrasilver derivative [Ag4 (1) 2](PF6) 4. The silver (I) complexes …

Hexaarylbenzene: evolution of properties and applications of multitalented scaffold

V Vij, V Bhalla, M Kumar - Chemical Reviews, 2016 - ACS Publications
The easily rotatable peripheral aromatic rings around central benzene in hexaarylbenzene
(HAB) derivatives create a very intriguing nonplanar, propeller-shaped geometry. Because …

Template Synthesis of Three‐Dimensional Hexakisimidazolium Cages

LY Sun, N Sinha, T Yan, YS Wang… - Angewandte Chemie …, 2018 - Wiley Online Library
A procedure for the synthesis of three‐dimensional hexakisimidazolium cage compounds
has been developed. The reaction of the trigonal trisimidazolium salts H3L (PF6) 3 …

Gold (I)“click” 1, 2, 3-triazolylidenes: Synthesis, self-assembly and catalysis

KJ Kilpin, USD Paul, AL Lee, JD Crowley - Chemical communications, 2011 - pubs.rsc.org
Gold( i ) “click” 1,2,3-triazolylidenes: synthesis, self-assembly and catalysis - Chemical
Communications (RSC Publishing) DOI:10.1039/C0CC02185G Royal Society of Chemistry …

Postsynthetic modification of dicarbene-derived metallacycles via photochemical [2+ 2] cycloaddition

YF Han, GX Jin, FE Hahn - Journal of the American Chemical …, 2013 - ACS Publications
Molecular squares obtained from two olefin-bridged bis (NHC) ligands, NHC–Ar–C C–Ar–
NHC, and two Ag+ or Au+ ions undergo postsynthetic modifications via a UV-irradiation …