A review of small molecule diffusion in polyolefins

NE Schlotter, PY Furlan - Polymer, 1992 - Elsevier
The transport of small molecules in polyolefins is a subject of both technical and commercial
importance. It is technically important because the factors, such as morphology and …

ATR-FTIR spectroscopic studies of the structure and permeability of sulfonated poly (ether sulfone) membranes. Part 2.—Water diffusion processes

MR Pereira, J Yarwood - Journal of the Chemical Society, Faraday …, 1996 - pubs.rsc.org
Attenuated total reflection (ATR) FTIR spectroscopy has been used to study the diffusion of
water into sulfonated poly (ether sulfone) films as a function of film thickness, preparation …

Time‐resolved Fourier transform infrared/attenuated total reflection spectroscopy for the measurement of molecular diffusion in polymers

YA Elabd, MG Baschetti… - Journal of Polymer Science …, 2003 - Wiley Online Library
Over the past 2 decades, the use of time‐resolved Fourier transform infrared/attenuated total
reflection (ATR) spectroscopy for the measurement of diffusion in polymers has grown. ATR …

The initial stages of Case II diffusion at low penetrant activities

RC Lasky, EJ Kramer, CY Hui - Polymer, 1988 - Elsevier
Rutherford backscattering spectrometry (R BS) has been used to measure the volume
fraction versus depth profiles of iodohexane vapour diffusing into glassy polystyrene. At …

Temperature dependence of case II diffusion

RC Lasky, EJ Kramer, CY Hui - Polymer, 1988 - Elsevier
Rutherford backscattering spectrometry was used to measure the front velocity V and the
local volume fraction∅(x) versus depth x of iodohexane in polystyrene as a function of …

Transport of plasticizing penetrants in glassy polymers

AR Berens - 1990 - ACS Publications
This survey of recent studies correlates the transport kinetics and equilibria of organic
vapors and liquids in glassy polymers with the molecular size, interaction parameter, and …

ATR-FTIR spectroscopic studies of the structure and permeability of sulfonated poly (ether sulfone) membranes Part 3.—Effects of sorption and desorption, and of …

S Hajatdoost, J Yarwood - Journal of the Chemical Society, Faraday …, 1997 - pubs.rsc.org
The diffusion of water into SPEES/PES polysulfone thin films, with different degrees of
sulfonation, has been studied in situ using the FTIR-ATR (attenuated total reflection) …

Quantitative nuclear magnetic resonance imaging of liquids in swelling polymers

TM Hyde, LF Gladden, MR Mackley… - Journal of Polymer …, 1995 - Wiley Online Library
The variation of nuclear magnetic resonance (NMR) relaxation parameters (T1, T2) within a
polymer during swelling, limits the absolute accuracy with which liquid concentration profiles …

Improved technique for cross-sectional imaging of thin polymer films by transmission electron microscopy

M Kunz, K Shull - Polymer, 1993 - Elsevier
An improved method for obtaining cross-sectional images of thin polymer films by
transmission electron microscopy is described. Two examples are described in order to …

Temperature dependence of methanol transport in spherical PMMA beads

PI Lee - Polymer, 1993 - Elsevier
The effect of temperature on the kinetics of methanol transport in PMMA has been
investigated for the first time in spherical sample geometry over the temperature range of 25 …