Accelerated reactions of amines with carbon dioxide driven by superacid at the microdroplet interface
Microdroplets display distinctive interfacial chemistry, manifested as accelerated reactions
relative to those observed for the same reagents in bulk. Carbon dioxide undergoes C–N …
relative to those observed for the same reagents in bulk. Carbon dioxide undergoes C–N …
On the formation of hydrogen peroxide in water microdroplets
Recent reports on the formation of hydrogen peroxide (H2O2) in water microdroplets
produced via pneumatic spraying or capillary condensation have garnered significant …
produced via pneumatic spraying or capillary condensation have garnered significant …
Enhanced condensation kinetics in aqueous microdroplets driven by coupled surface reactions and gas-phase partitioning
M Li, S Yang, M Rathi, S Kumar, CS Dutcher… - Chemical …, 2024 - pubs.rsc.org
Although aqueous microdroplets have been shown to exhibit enhanced chemical reactivity
compared to bulk solutions, mechanisms for these enhancements are not completely …
compared to bulk solutions, mechanisms for these enhancements are not completely …
Busting the myth of spontaneous formation of H 2 O 2 at the air–water interface: contributions of the liquid–solid interface and dissolved oxygen exposed
Recent reports on the spontaneous formation of hydrogen peroxide (H2O2) at the air–water
and solid–water interfaces challenge our current understanding of aquatic chemistry and …
and solid–water interfaces challenge our current understanding of aquatic chemistry and …
pH jump kinetics in colliding microdroplets: accelerated synthesis of azamonardine from dopamine and resorcinol
Recent studies report the dramatic acceleration of chemical reactions in micron-sized
compartments. In the majority of these studies the exact acceleration mechanism is unknown …
compartments. In the majority of these studies the exact acceleration mechanism is unknown …
Visualizing partial solvation at the air–water interface
Despite significant research, the mechanistic nuances of unusual reactivity at the air–water
interface, especially in microdroplets, remain elusive. The likely contributors include electric …
interface, especially in microdroplets, remain elusive. The likely contributors include electric …
Experimental evidence that halogen bonding catalyzes the heterogeneous chlorination of alkenes in submicron liquid droplets
A key challenge in predicting the multiphase chemistry of aerosols and droplets is
connecting reaction probabilities, observed in an experiment, with the kinetics of individual …
connecting reaction probabilities, observed in an experiment, with the kinetics of individual …
Time-dependent photoemission from droplets: influence of size and charge on the photophysics near the surface
Photoemission from submicrometer droplets containing a mixture of dioctyl phthalate and
dioctyl sebacate was investigated by femtosecond and nanosecond photoionization …
dioctyl sebacate was investigated by femtosecond and nanosecond photoionization …