Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Stable metal–organic frameworks: design, synthesis, and applications

S Yuan, L Feng, K Wang, J Pang, M Bosch… - Advanced …, 2018 - Wiley Online Library
Metal–organic frameworks (MOFs) are an emerging class of porous materials with potential
applications in gas storage, separations, catalysis, and chemical sensing. Despite numerous …

Evolution of water structures in metal-organic frameworks for improved atmospheric water harvesting

N Hanikel, X Pei, S Chheda, H Lyu, WS Jeong, J Sauer… - Science, 2021 - science.org
Although the positions of water guests in porous crystals can be identified, determination of
their filling sequence remains challenging. We deciphered the water-filling mechanism for …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Tunable confined aliphatic pore environment in robust metal–organic frameworks for efficient separation of gases with a similar structure

J Zhou, T Ke, F Steinke, N Stock, Z Zhang… - Journal of the …, 2022 - ACS Publications
The fine-tuning of the pore structure of metal–organic frameworks (MOFs) is of critical
importance to developing energy-efficient processes for the challenging separation of …

The thermal stability of metal-organic frameworks

C Healy, KM Patil, BH Wilson, L Hermanspahn… - Coordination Chemistry …, 2020 - Elsevier
In order to systematically engineer the properties of crystalline and amorphous metal-
organic frameworks (MOFs) towards practical application, a thorough understanding of their …

Ratiometric fluorescence sensing of metal-organic frameworks: Tactics and perspectives

L Chen, D Liu, J Peng, Q Du, H He - Coordination Chemistry Reviews, 2020 - Elsevier
Metal-organic frameworks (MOFs) are an important class of inorganic-organic hybrid crystals
with applications in various fields. In last ten years, MOFs-based fluorescence sensing has …

Structures of metal–organic frameworks with rod secondary building units

A Schoedel, M Li, D Li, M O'Keeffe… - Chemical Reviews, 2016 - ACS Publications
Rod MOFs are metal–organic frameworks in which the metal-containing secondary building
units consist of infinite rods of linked metal-centered polyhedra. For such materials, we …

Metal-organic frameworks bearing free carboxylic acids: Preparation, modification, and applications

BN Bhadra, I Ahmed, HJ Lee, SH Jhung - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-organic frameworks (MOFs) bearing free–COOH groups (MOF-COOHs) have attracted
particular attention in the field of MOF research. Several MOF-COOHs have been prepared …

Multifunctional metal–organic frameworks: from academia to industrial applications

P Silva, SMF Vilela, JPC Tomé, FAA Paz - Chemical Society Reviews, 2015 - pubs.rsc.org
After three decades of intense and fundamental research on metal–organic frameworks
(MOFs), is there anything left to say or to explain? The synthesis and properties of MOFs …