Oxygen loss in layered oxide cathodes for Li-ion batteries: mechanisms, effects, and mitigation

H Zhang, H Liu, LFJ Piper, MS Whittingham… - Chemical …, 2022 - ACS Publications
Layered lithium transition metal oxides derived from LiMO2 (M= Co, Ni, Mn, etc.) have been
widely adopted as the cathodes of Li-ion batteries for portable electronics, electric vehicles …

Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

M Zhang, DA Kitchaev, Z Lebens-Higgins… - Nature Reviews …, 2022 - nature.com
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …

Engineering Na+-layer spacings to stabilize Mn-based layered cathodes for sodium-ion batteries

W Zuo, X Liu, J Qiu, D Zhang, Z Xiao, J Xie… - Nature …, 2021 - nature.com
Layered transition metal oxides are the most important cathode materials for Li/Na/K ion
batteries. Suppressing undesirable phase transformations during charge-discharge …

Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques

W Zuo, M Luo, X Liu, J Wu, H Liu, J Li… - Energy & …, 2020 - pubs.rsc.org
Due to their high specific capacities beyond 250 mA hg− 1, lithium-rich oxides have been
considered as promising cathodes for the next generation power batteries, bridging the …

The predicted persistence of cobalt in lithium-ion batteries

WE Gent, GM Busse, KZ House - Nature Energy, 2022 - nature.com
Cobalt, widely used in the layered oxide cathodes needed for long-range electric vehicles
(EVs), has been identified as a key EV supply bottleneck. Many reports have proposed that …

Multiscale crystal field effect for high-performance ultrahigh-Ni layered cathode

L Ni, H Chen, J Gao, Y Mei, H Wang, W Deng, G Zou… - ACS …, 2023 - ACS Publications
Further popularization of ultrahigh-Ni layered cathodes for high-energy lithium-ion batteries
(LIBs) is hampered by their grievous structural and interfacial degeneration upon cycling …

Regulating surface oxygen activity by perovskite‐coating‐stabilized ultrahigh‐nickel layered oxide cathodes

L Wang, G Liu, R Wang, X Wang, L Wang… - Advanced …, 2023 - Wiley Online Library
Ultrahigh‐Ni layered oxides are proposed as promising cathodes to fulfill the range demand
of electric vehicles; yet, they are still haunted by compromised cyclability and thermal …

Anionic redox reaction and structural evolution of Ni-rich layered oxide cathode material

S Li, Z Liu, L Yang, X Shen, Q Liu, Z Hu, Q Kong, J Ma… - Nano Energy, 2022 - Elsevier
The Ni-rich layer-structured oxide is one of the most promising candidate cathode materials
for the high energy-density Li-ion batteries. However, the commercial applications of these …

Cycling mechanism of Li2MnO3: Li–CO2 batteries and commonality on oxygen redox in cathode materials

Z Zhuo, K Dai, R Qiao, R Wang, J Wu, Y Liu, J Peng… - Joule, 2021 - cell.com
Li 2 MnO 3 has been considered to be a representative Li-rich compound with active
debates on oxygen activities. Here, by evaluating the Mn and O states in the bulk and on the …