Lanthanide circularly polarized luminescence: bases and applications

F Zinna, L Di Bari - Chirality, 2015 - Wiley Online Library
Lanthanide (III) luminescence is very characteristic: it is characterized by narrow emission
bands, large Stokes shift, and a long excited state lifetime. Moreover, chiral lanthanide …

Lanthanide complexes as chiral probes exploiting circularly polarized luminescence

R Carr, NH Evans, D Parker - Chemical Society Reviews, 2012 - pubs.rsc.org
Optical probes that provide information about local chirality have been developed based on
changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide …

Biomolecule‐Based Circularly Polarized Luminescent Materials: Construction, Progress, and Applications

Y Dai, J Chen, C Zhao, L Feng… - Angewandte Chemie …, 2022 - Wiley Online Library
Chiral materials related to circularly polarized luminescence (CPL) make up a rapidly
developing new field that has broad application prospects in optoelectronic devices …

Rapid time-resolved Circular Polarization Luminescence (CPL) emission spectroscopy

LE MacKenzie, LO Pålsson, D Parker, A Beeby… - Nature …, 2020 - nature.com
Circular polarisation luminescence (CPL) emission spectroscopy is a powerful tool for
probing the fundamental chiroptical features of optically emissive chiral molecular systems …

EuroTracker® dyes: design, synthesis, structure and photophysical properties of very bright europium complexes and their use in bioassays and cellular optical …

SJ Butler, M Delbianco, L Lamarque… - Dalton …, 2015 - pubs.rsc.org
The development of the brightest luminescent europium (III) complexes is traced, including
analysis of the C3-symmetric core complex based on a functionalized triazacyclononane …

Very bright, enantiopure europium (III) complexes allow time-gated chiral contrast imaging

AT Frawley, R Pal, D Parker - Chemical Communications, 2016 - pubs.rsc.org
Very bright, enantiopure europium( iii ) complexes allow time-gated chiral contrast imaging -
Chemical Communications (RSC Publishing) DOI:10.1039/C6CC07313A Royal Society of …

Circularly polarized luminescence and coordination geometries in mononuclear lanthanide (III) complexes

L Llanos, P Cancino, P Mella, P Fuentealba… - Coordination Chemistry …, 2024 - Elsevier
The interest in chirality crosses many research areas in chemistry, physics, materials, and
life sciences. Besides the fundamental importance of chiral recognition in biological …

Circularly polarised luminescence in enantiopure samarium and europium cryptates

E Kreidt, L Arrico, F Zinna, L Di Bari… - Chemistry–A European …, 2018 - Wiley Online Library
Circularly polarised luminescence (CPL) is a chiroptical phenomenon gaining more and
more attention, as the availability of the necessary spectrometers is getting better and first …

New class of bright and highly stable chiral cyclen europium complexes for circularly polarized luminescence applications

L Dai, WS Lo, ID Coates, R Pal, GL Law - Inorganic chemistry, 2016 - ACS Publications
High g lum values of+ 0.30 (Δ J= 1, 591 nm, in DMSO) and− 0.23 (Δ J= 1, 589 nm, in H2O)
were recorded in our series of newly designed macrocyclic europium (III) complexes. A …

Unlocking same‐sign CPL: solvent effects on spectral form and racemisation kinetics in nine‐coordinate chiral europium (III) complexes

DF De Rosa, M Starck, D Parker… - Chemistry–A European …, 2024 - Wiley Online Library
Understanding the factors that shape the circularly polarised luminescence (CPL) emission
profiles of europium (III)‐based CPL emitters to have specific sign properties, eg …