Dienes polymerization: Where we are and what lies ahead

G Ricci, G Pampaloni, A Sommazzi, F Masi - Macromolecules, 2021 - ACS Publications
Recently, the research activity in the field of the stereospecific polymerization of conjugated
dienes has focused on the use of catalysts based on organometallic complexes having a …

Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis

Y Champouret, OH Hashmi, M Visseaux - Coordination Chemistry Reviews, 2019 - Elsevier
Catalysis based on well-defined iron complexes has experienced a very strong growth over
the last decade, driven by the need to develop a chemistry that is increasingly in line with …

Noncovalent interactions in late transition metal-catalyzed polymerization of olefins

H Zheng, H Gao - Macromolecules, 2024 - ACS Publications
Transition metal-catalyzed olefin polymerization dominates in the polyolefin field, and we
still have limited control over a catalyst's behavior. In addition to traditional steric and …

Synthesis of various branched ultra-high-molecular-weight polyethylenes using sterically hindered acenaphthene-based α-diimine Ni (II) catalysts

L Guo, K Lian, W Kong, S Xu, G Jiang, S Dai - Organometallics, 2018 - ACS Publications
A series of highly sterically hindered acenaphthene-based α-diimine nickel complexes with
the remote R group in 4-position of diarylmethyl moiety have been synthesized and …

Half-sandwich iridium and ruthenium complexes: effective tracking in cells and anticancer studies

JJ Li, L Guo, Z Tian, S Zhang, Z Xu, Y Han, R Li… - Inorganic …, 2018 - ACS Publications
Half-sandwich metal-based anticancer complexes suffer from uncertain targets and
mechanisms of action. Herein we report the observation of the images of half-sandwich …

Highly Stereoregular 1,3-Butadiene and Isoprene Polymers through Monoalkyl-N-Aryl-Substituted Iminopyridine Iron Complex-Based Catalysts: Synthesis and …

G Ricci, G Leone, G Zanchin, B Palucci… - …, 2021 - ACS Publications
Some novel monoalkyl-N-aryl-substituted iminopyridine iron chloride complexes, differing in
the nature of the substituent at the iminic carbon and at the ortho position of the aryl ring …

Structurally Rigid (8-(Arylimino)-5,6,7-trihydroquinolin-2-yl)-methyl Acetate Cobalt Complex Catalysts for Isoprene Polymerization with High Activity and cis-1,4 …

N Yousuf, Y Ma, Q Mahmood, W Zhang, M Liu, R Yuan… - Catalysts, 2023 - mdpi.com
A series of cobalt complexes bearing (8-(arylimino)-5, 6, 7-trihydroquinolin-2-yl) methyl
acetate ligand framework were prepared using a one-pot synthesis method. These …

Half-sandwich iridium (III) and ruthenium (II) complexes containing P^ P-chelating ligands: A new class of potent anticancer agents with unusual redox features

JJ Li, M Tian, Z Tian, S Zhang, C Yan, C Shao… - Inorganic …, 2018 - ACS Publications
A series of half-sandwich IrIII pentamethylcyclopentadienyl and RuII arene complexes
containing P^ P-chelating ligands of the type [(Cpx/arene) M (P^ P) Cl] PF6, where M= Ir …

Enhancing thermal stability in aminopyridine iron (II)-catalyzed polymerization of conjugated dienes

C Jing, L Wang, G Zhu, H Hou, L Zhou, Q Wang - Organometallics, 2020 - ACS Publications
A library of well-defined aminopyridine iron (II) precatalysts with a tertiary amine moiety have
been prepared and serve as highly efficient precatalysts for polymerization of isoprene and …

Synthesis, characterization and catalytic property studies for isoprene polymerization of iron complexes bearing unionized pyridine-oxime ligands

M Zhao, Y Ma, X Zhang, L Wang, G Zhu, Q Wang - Polymers, 2022 - mdpi.com
Iron complexes of the types [Fe (HL) 2Cl2](Fe1: HL1= pyridine-2-aldoxime; Fe2: HL2= 6-
methylpyridine-2-aldoxime; Fe3: HL3= phenyl-2-pyridylketoxime; Fe4: HL4 …