This Minireview describes the scope of the halogen–magnesium exchange. It shows that the
use of the turbo‐Grignard reagent (iPrMgCl⋅ LiCl) greatly enhances the rate of the Br–and I …

For almost 40 years, difluoromethylene phosphonates have proven to be versatile molecular
tools in biochemical studies owing to their close resemblance to naturally occurring …

A facile one-pot approach for the azidodifluoromethylation of aldehydes via in situ-
generated azidodifluoromethenide (N3CF2–) utilizing commercially available TMSCF2Br …

A new method for the on‐site preparation of tetrafluoroethylene (TFE) and a procedure for its
efficient use in pentafluoroethylation by fluoride addition were developed by using a simple …

Chemoproteomic profiling of cysteines has emerged as a powerful method for screening the
proteome-wide targets of cysteine-reactive fragments, drugs, and natural products. Herein …

A new fluorinated azidoethane─ 1-azido-1, 1, 2, 2-tetrafluoroethane─ was prepared in
quantitative yield by the addition of an azide anion to tetrafluoroethylene in a protic medium …

A straightforward synthesis of 1-azido-2-bromo-1, 1, 2, 2-tetrafluoroethane on a multigram
scale from 1, 2-dibromotetrafluoroethane and sodium azide in a novel process initiated by …

The activation of SF6 at [Pt (PR3) 2] R= Cy, iPr complexes in the presence of PR3 led
selectively and in an unprecedented reaction route to the generation of the SF3 complexes …

Abstract A palladium (0)‐catalyzed three‐component reaction of 2‐iodo‐2, 2‐
difluoroacetophenones, alkynes and arylboronic acids is introduced for the synthesis of 1 …

The incorporation of perfluoroalkyl groups into molecules leads to unique properties, and
perfluoroalkylation reagents play a vital role. Although various types of perfluoroalkylation …