Electrochemiluminescence from single molecule to imaging
The revolution of quantum physics about a hundred years ago has greatly promoted the
development of theoretical chemistry, which enables the understanding of the relationship …
development of theoretical chemistry, which enables the understanding of the relationship …
Nanoscale molecular layers for memory devices: challenges and opportunities for commercialization
The modern era of digital computing systems is deeply embedded around memory devices,
which store an ocean of information accessible by an electronic gadget. Such electronic …
which store an ocean of information accessible by an electronic gadget. Such electronic …
Confined water's dielectric constant reduction is due to the surrounding low dielectric media and not to interfacial molecular ordering
JF Olivieri, JT Hynes, D Laage - The Journal of Physical Chemistry …, 2021 - ACS Publications
Liquid water confined within nanometer-sized channels exhibits a surprisingly low dielectric
constant along the direction orthogonal to the channel walls. This is typically assumed to …
constant along the direction orthogonal to the channel walls. This is typically assumed to …
Direct evidence for a sequential electron transfer–proton transfer mechanism in the PCET reduction of a metal hydroxide catalyst
The proton-coupled electron transfer (PCET) mechanism for the reaction Mox–OH+ e–+
H+→ Mred–OH2 was determined through the kinetic resolution of the independent electron …
H+→ Mred–OH2 was determined through the kinetic resolution of the independent electron …
Helmholtz capacitance of aqueous NaCl solutions at the au (100) electrode from polarizable and nonpolarizable molecular dynamics simulations
S Park, JG McDaniel - The Journal of Physical Chemistry C, 2022 - ACS Publications
Aqueous NaCl solutions at gold electrodes serve as prototypical electrochemical interfaces.
A fundamental property of these interfaces is the differential capacitance, from which …
A fundamental property of these interfaces is the differential capacitance, from which …
Reorganization Energies for Interfacial Proton-Coupled Electron Transfer to a Water Oxidation Catalyst
The reorganization energy (λ) for interfacial electron transfer (ET) and proton-coupled ET
(PCET) from a conductive metal oxide (In2O3: Sn, ITO) to a surface-bound water oxidation …
(PCET) from a conductive metal oxide (In2O3: Sn, ITO) to a surface-bound water oxidation …
Electrochemical response of surface-attached redox DNA governed by low activation energy electron transfer kinetics
The mechanism responsible for electron transport within layers of redox DNA anchored to
electrodes has been extensively studied over the last twenty years, but remains …
electrodes has been extensively studied over the last twenty years, but remains …
Nanogap-resolved adsorption-coupled electron transfer by scanning electrochemical microscopy: Implications for electrocatalysis
N Kurapati, DC Janda, RJ Balla, SH Huang… - Analytical …, 2022 - ACS Publications
Here, we demonstrate for the first time that the mechanism of adsorption-coupled electron-
transfer (ACET) reactions can be identified experimentally. The electron transfer (ET) and …
transfer (ACET) reactions can be identified experimentally. The electron transfer (ET) and …
Perspectives on dye sensitization of nanocrystalline mesoporous thin films
Recent advances in our mechanistic understanding of dye-sensitized electron transfer
reactions occurring at metal oxide interfaces are described. These advances were enabled …
reactions occurring at metal oxide interfaces are described. These advances were enabled …
Understanding electron transfer reactions using constrained density functional theory: complications due to surface interactions
The kinetic rates of electrochemical reactions depend on electrodes and molecules in
question. In a flow battery, where the electrolyte molecules are charged and discharged on …
question. In a flow battery, where the electrolyte molecules are charged and discharged on …