Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Palladium/norbornene cooperative catalysis

J Wang, G Dong - Chemical reviews, 2019 - ACS Publications
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

[HTML][HTML] Synthesis of indoles, indolines, and carbazoles via palladium-catalyzed C–H activation

AJ Rago, G Dong - Green synthesis and catalysis, 2021 - Elsevier
The construction of indole, indoline and carbazole heterocycles has been of significant
interest in the synthetic community over the last century due to their prevalence in natural …

Palladium/Norbornene‐Catalyzed Direct Vicinal Di‐Carbo‐Functionalization of Indoles: Reaction Development and Mechanistic Study

X Liu, Y Zhou, X Qi, R Li, P Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Methods that can simultaneously install multiple different functional groups to heteroarenes
via C− H functionalizations are valuable for complex molecule synthesis, which, however …

Modular and stereoselective synthesis of C-aryl glycosides via Catellani reaction

W Lv, Y Chen, S Wen, D Ba… - Journal of the American …, 2020 - ACS Publications
In this work, we describe a Catellani-type C–H glycosylation to provide rapid access to
various highly decorated α-C-(hetero) aryl glycosides in a modular and stereoselective …

Structurally modified norbornenes: a key factor to modulate reaction selectivity in the palladium/norbornene cooperative catalysis

R Li, G Dong - Journal of the American Chemical Society, 2020 - ACS Publications
Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

Recent progress on Catellani reaction

Z Chen, F Zhang - Tetrahedron, 2023 - Elsevier
The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

Ortho-C–H methoxylation of aryl halides enabled by a polarity-reversed N–O reagent

X Liu, Y Fu, Z Chen, P Liu, G Dong - Nature Chemistry, 2023 - nature.com
Oxygen-substituted arenes widely exist in biologically important molecules and can serve as
versatile handles to install other functional groups. However, direct and site-selective …

Site‐Selective C− H Functionalization of Carbazoles

M Elsaid, R Ge, C Liu, D Maiti… - Angewandte Chemie …, 2023 - Wiley Online Library
Carbazole alkaloids hold great potential in pharmaceutical and material sciences. However,
the current approaches for C1 functionalization of carbazoles rely on the use of a pre …

Catellani reaction: an enabling technology for vicinal functionalization of aryl halides by palladium (0)/norbornene cooperative catalysis

S Dong, X Luan - Chinese Journal of Chemistry, 2021 - Wiley Online Library
The Catellani reaction, originally discovered by Catellani in 1997, and further developed by
Catellani, Lautens and others, has emerged as a powerful strategy for the synthesis of …