Single atom catalysts for selective methane oxidation to oxygenates

P Kumar, TA Al-Attas, J Hu, MG Kibria - ACS nano, 2022 - ACS Publications
Direct conversion of methane (CH4) to C1–2 liquid oxygenates is a captivating approach to
lock carbons in transportable value-added chemicals, while reducing global warming …

Role of H2O in Catalytic Conversion of C1 Molecules

L Jiang, K Li, WN Porter, H Wang, G Li… - Journal of the American …, 2024 - ACS Publications
Due to their role in controlling global climate change, the selective conversion of C1
molecules such as CH4, CO, and CO2 has attracted widespread attention. Typically, H2O …

Disentangling local interfacial confinement and remote spillover effects in oxide–oxide interactions

C Dong, R Mu, R Li, J Wang, T Song, Z Qu… - Journal of the …, 2023 - ACS Publications
Supported oxides are widely used in many important catalytic reactions, in which the
interaction between the oxide catalyst and oxide support is critical but still remains elusive …

Light-Induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-Temperature H2 Production from Methanol and Water

S Luo, H Song, F Ichihara, M Oshikiri… - Journal of the …, 2023 - ACS Publications
The structure and configuration of reaction centers, which dominantly govern the catalytic
behaviors, often undergo dynamic transformations under reaction conditions, yet little is …

Enhancing CO2 Electroreduction Performance through Si-Doped CuO: Stabilization of Cu+/Cu0 Sites and Improved C2 Product Selectivity

L Cheng, R Wang, W Si, Y Deng, J Li, Y Peng - ACS Catalysis, 2024 - ACS Publications
Cu-based catalysts leveraging Cu+/Cu0 active sites have emerged as pivotal for
synthesizing essential hydrocarbons and alcohols in electrochemical CO2 reduction, such …

Silver and copper dual single atoms boosting direct oxidation of methane to methanol via synergistic catalysis

B Yu, L Cheng, S Dai, Y Jiang, B Yang, H Li… - Advanced …, 2023 - Wiley Online Library
Rationally constructing atom‐precise active sites is highly important to promote their catalytic
performance but still challenging. Herein, this work designs and constructs ZSM‐5 …

High-Pressure Electro-Fenton Driving CH4 Conversion by O2 at Room Temperature

Y Song, X Yang, H Liu, S Liang, Y Cai… - Journal of the …, 2024 - ACS Publications
Electrochemical conversion of CH4 to easily transportable and value-added liquid fuels is
highly attractive for energy-efficient CH4 utilization, but it is challenging due to the low …

Efficient catalysts of surface hydrophobic Cu-BTC with coordinatively unsaturated Cu (I) sites for the direct oxidation of methane

W Li, Z Li, H Zhang, P Liu, Z Xie… - Proceedings of the …, 2023 - National Acad Sciences
Selective oxidation of methane to organic oxygenates over metal–organic frameworks
(MOFs) catalysts at low temperature is a challenging topic in the field of C1 chemistry …

Activation and Conversion of Methane to Syngas over ZrO2/Cu(111) Catalysts near Room Temperature

E Huang, N Rui, R Rosales, P Liu… - Journal of the American …, 2023 - ACS Publications
Enzymatic systems achieve the catalytic conversion of methane at room temperature under
mild conditions. In this study, varying thermodynamic and kinetic parameters, we show that …

Microscopic Investigation of H2 Reduced CuOx/Cu(111) and ZnO/CuOx/Cu(111) Inverse Catalysts: STM, AP-XPS, and DFT Studies

V Mehar, E Huang, R Shi, N Rui, R Rosales… - ACS …, 2023 - ACS Publications
Understanding the reduction mechanism of ZnO/CuO x interfaces by hydrogen is of great
importance in advancing the performance of industrial catalysts used for CO and CO2 …